萘系双环芳烃缩聚方法研究进展  

Research progress in preparation of mesophase pitch by polycondensation of naphthalene-based bicyclic aromatic hydrocarbons

作　　者：张举鹏 石利斌 彭东岳 罗洋 管翠诗 ZHANG Jupeng;SHI Libin;PENG Dongyue;LUO Yang;GUAN Cuishi(SINOPEC Research Institute of Petroleum Processing Co.,Ltd.,Bejing 100083,China)

机构地区：[1]中石化石油化工科学研究院有限公司,北京100083

出　　处：《应用化工》2024年第6期1394-1397,共4页Applied Chemical Industry

基　　金：国家自然科学基金项目(22309212);中国石油化工股份有限公司课题(123075)。

摘　　要：综述了萘系双环芳烃的结构特性、应用领域及其对环境和健康的潜在影响。对非催化热缩聚、压力诱导缩聚以及多种催化缩聚方法进行了详细分析,特别是对AlCl_(3)、HF/BF_(3)、过渡金属和固体超强酸SO_(4)^(2-)/M_(x)O_(y)等催化机制进行了深入探讨,揭示其缩聚反应的机理、优势与局限性。最后提出了在萘系双环芳烃缩聚领域尚未解决的问题和挑战,为推动相关领域的科学研究和技术发展提供了深入的参考。This paper reviews the structural characteristics,application fields,and potential impacts on the environment and health of naphthalene-based PAHs.It provides a detailed analysis of non-catalytic thermal condensation,pressure-induced condensation,and various catalytic condensation methods,especially the catalytic mechanisms of AlCl_(3),HF/BF_(3),transition metals,and solid superacids SO_(4)^(2-)/M_(x)O_(y),revealing their condensation reaction mechanisms,advantages,and limitations.Finally,the unresolved issues and challenges in the field of naphthalene-based PAH condensation are proposed,providing an in-depth reference for promoting scientific research and technological development in related fields.

关 键 词：双环芳烃 萘 缩聚 反应机理 催化 

分 类 号：TQ241.5[化学工程—有机化工] O625[理学—有机化学]