Side-Chain Type Ferrocene Macrocycles  

作　　者：Bin Lan Jindong Xu Lingyun Zhu Xinyu Chen Hideya Kono Peihan Wang Xin Zuo Jianfeng Yan Akiko Yagi Yongshen Zheng Songhua Chen Yaofeng Yuan Kenichiro Itami Yuanming Li 

机构地区：[1]Key Laboratory of Molecule Synthesis and Function Discovery(Fujian Province University),College of Chemistry,Fuzhou University,Fuzhou 350108,China [2]Institute of Transformative Bio-Molecules(WPI-ITbM),Nagoya University,Nagoya 464-8602,Japan [3]School of Materials Science and Engineering,National Institute for Advanced Materials,Nankai University,Tianjin 300350,China [4]Institute of Transformative Bio-Molecules(WPIITbM),Nagoya University,Nagoya 464-8602,Japan [5]College of Chemistry and Material Science,Longyan University,Longyan 364012,China

出　　处：《Precision Chemistry》2024年第4期143-150,共8页精准化学（英文）

基　　金：supported from National Natural Science Foundation of China(No.22071025);the Natural Science Fund of Fujian Province,China(No.2022J011152).

摘　　要：A class of side-chain type ferrocene macrocycles with a radially conjugated system is introduced in this study.The stereo configurations of these ferrocene rings were determined through single-crystal X-ray diffraction analysis.Notably,in the solid state,the ferrocene rings exhibit a distinctive herringbone stacking pattern imposed by a ferrocene-to-ring host−guest interaction.Through UV−vis absorption spectroscopy,electrochemical measurements,and theoretical calculations,valuable insights into the electronic properties of these rings were obtained.In addition,the single crystal of macrocycle A_(2)B demonstrates a second-order nonlinear optical response.As a class of organometallic nanorings,this work holds great potential for further exploration in the fields of organometallic chemistry,molecular electronics,and host−guest chemistry.

关 键 词：FERROCENE Conjugated Macrocycles Organometallic Macrocycles Second-Order Nonlinear Optical NANORING 

分 类 号：O62[理学—有机化学]