Z型全氟聚醚的合成及应用研究进展  

Progress in Synthesis and Application of Z-type Perfluoropolyethers

作　　者：张文 刘波[1] 张鸣[1] 杨旭仓 钟志刚 ZHANG Wen;LIU Bo;ZHANG Ming;YANG Xucang;ZHONG Zhigang(Zhonghao Chenguang Research Institute of Chemical Industry Co.,Ltd.,Sichuan Key Laboratory of Organic Fluorine Materials,Zigong 643201,China)

机构地区：[1]中昊晨光化工研究院有限公司,有机氟材料四川省重点实验室,四川自贡643201

出　　处：《有机氟工业》2024年第2期17-22,共6页Organo-Fluorine Industry

摘　　要：对四氟乙烯光氧化反应、过氧基团的去除和端基处理合成Z型全氟聚醚的过程进行了系统论述,并深入分析了光氧化反应机理。按照Z型全氟聚醚端基类型的差异,分别介绍了带惰性端基和功能性端基Z型全氟聚醚的应用进展,分析了现有合成工艺存在的问题及解决方法,以期为Z型全氟聚醚的合成及应用研究提供有益参考。The synthesis processes of Z-type perfluoropolyethers,such as photooxidation reaction of tetrafluo-roethylene,removal of peroxy groups and end-group treatment were systematically discussed,and the reaction mechanism of photooxidation was deeply analyzed.According to the differences in the end group types of Z-type perfluoropolyethers,the application progress of Z-type perfluoropolyethers with inert and functional end groups was introduced,and synthetic conundrums of Z-type perfluoropolyethers were analyzed,with a view to providing useful references for the synthesis and application research of Z-type perfluoropolyethers.

关 键 词：Z型全氟聚醚 光氧化反应 过氧化物 端基氟化 

分 类 号：TQ317[化学工程—高聚物工业]