二维介孔材料的合成方法、设计与应用研究进展  

Research Progress on the Synthesis and Application of Two-Dimensional Mesoporous Materials

作　　者：李英维 韩吉 关卜源 LI Ying-Wei;HAN Ji;GUAN Bu-Yuan(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China;International Center of Future Science,Jilin University,Changchun 130012,China)

机构地区：[1]吉林大学化学学院,无机合成与制备化学国家重点实验室,长春130012 [2]吉林大学未来科学与国际合作联合实验室,长春130012

出　　处：《应用化学》2024年第6期767-782,共16页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金(No.22375071)资助。

摘　　要：由于具有可调的孔道结构、可控的化学组成以及广阔的应用前景,介孔材料近年来引起了科研工作者们的广泛关注。与传统的三维介孔材料相比,二维介孔材料具有更大的比表面积,更短的扩散距离,以及更高的活性位点暴露程度。因此,二维介孔材料在催化、气体吸附、能源存储与转化等应用领域中展现出十分优异的性能。本文从自下而上和自上而下2种合成策略出发,系统梳理了近10年来二维介孔材料合成方法的研究进展,并全面总结了二维介孔材料在电化学储能、电催化、光催化和气体传感领域的应用。最后,本文对二维介孔材料的未来发展方向与挑战进行了展望。Mesoporous materials have attracted significant research interests due to its tunable pore structure,controllable chemical composition,and broad application prospects.Compared with traditional threedimensional mesoporous materials,two-dimensional mesoporous materials have larger specific surface area,shorter diffusion distance,and higher exposure of active sites.Therefore,two-dimensional mesoporous materials exhibit excellent performance in applications such as catalysis,gas adsorption,as well as energy storge and conversion.In this review,based on bottom-up and top-down synthetic strategies,we summarize the research progress of synthetic methods of two-dimensional mesoporous materials in recent years.Then,we discuss their applications in electrochemical energy storage,electrocatalysis,photocatalysis,and gas sensing.Finally,we provide an outlook on the future development directions and challenges of twodimensional mesoporous materials.

关 键 词：介孔材料 二维材料 纳米材料 电化学储能 电催化 光催化 气体传感器 

分 类 号：O611.4[理学—无机化学]