火焰法与喷雾干燥法共合成固体氧化物燃料电池阴极La_(0.6)Sr_(0.4)CoO_(3–δ)–Ce_(0.8)Gd_(0.2)O_(2–δ)的微观结构与性能分析  

Microstructure and Performance Analysis of Solid Oxide Fuel Cell La_(0.6)Sr_(0.4)CoO_(3-δ)-Ce_(0.8)Gd_(0.2)O_(2-δ)Cathode Synthesized by Flame Spray Pyrolysis and Spray Drying

作　　者：王天齐 相龙凯 高展 张毅然 倪娜 屠恒勇 朱磊[2] 黄震[1,2] WANG Tianqi;XIANG Longkai;GAO Zhan;ZHANG Yiran;NI Na;TU Hengyong;ZHU Lei;HUANG Zhen(College of Smart Energy,Shanghai Jiao Tong University,Shanghai 200240,China;School of Mechanical Engineering,Shanghai Jiao Tong University,Shanghai 200240,China)

机构地区：[1]上海交通大学国家电投智慧能源创新学院,上海200240 [2]上海交通大学机械与动力工程学院,上海200240

出　　处：《硅酸盐学报》2024年第6期1810-1819,共10页Journal of The Chinese Ceramic Society

基　　金：上海市市级科技重大专项;上海市基础研究试点项目(21ZQ1400207);上海市科技创新行动计划(21DZ1206400)。

摘　　要：实现阴极结构的纳米化以提升电极三相界面长度,是提升固体氧化物燃料电池(SOFC)性能的有效途径。基于火焰喷雾热解法和喷雾干燥法,分别一步法合成纳米级和亚微米级的La_(0.6)Sr_(0.4)CoO_(3-δ)-Ce_(0.8)Gd_(0.2)O_(2-δ)复相材料。将2种粒径范围材料按照不同质量比混合,制成氧化钇部分稳定氧化锆电解质支撑的固体氧化物燃料电池的阴极,并系统分析电池性能与结构特征。结果表明,喷雾干燥合成材料与火焰喷雾热解合成材料的质量比为70:30时,SOFC电化学性能最优,850℃时最大功率密度为0.47 W/cm^(2),面电阻为0.62Ω·cm^(2),相应的欧姆阻抗和极化阻抗为0.36Ω·cm^(2)和0.26Ω·cm^(2)。实验证明,混合不同粒径颗粒制成的SOFC阴极,可有效构建电子–离子导通网络,并形成更多的三相界面和反应活性位点,从而获得较好的电化学性能。本研究为固体氧化物燃料电池阴极材料微观结构和性能优化提供了新的思路。Introduction Optimizing the nanostructure of the cathode is an effective approach to enhance the performance of solid oxide fuel cells at a triple-phase boundary(TPB).The most commonly used method is an impregnation method,which can produce nano-sized particles on the cathode framework structure.However,it is not able to achieve the related large-scale application due to its laborious preparation process and unstable performance.In this paper,nano-sized and submicron-sized composite powders of La_(0.6)Sr_(0.4)CoO_(3-δ)-Ce_(0.8)Gd_(0.2)O_(2-δ)(LSC−GDC)were synthesized by flame spray pyrolysis(FSP)and spray drying(SD)methods for the preparation of cathode,respectively.Methods A uniform submicron-sized LSC−GDC composite powder was prepared by SD with a solution of metal nitrates as a precursor solution.Also,a uniform nano-sized LSC−GDC composite powder was directly synthesized by FSP with a solution of metal acetates as a precursor solution.The submicron-sized and nano-sized powders were blended in different mass ratios(i.e.,100:0,90:10,80:20,70:30,60:40,50:50,and 40:60)to produce cathode slurries.These slurries were then screen-printed onto the button cells of NiO−GDC|GDC|3YSZ|GDC|LSC−GDC|LSC structure with an effective electrode area of approximately 0.5 cm^(2).The voltammetric characteristics of the cells were tested by an electrochemical workstation.The electrochemical characterization was performed by electrochemical impedance spectroscopy(EIS)at open circuit voltage(OCV),and the impedance spectra were analyzed via distribution of relaxation time(DRT)analysis.Results and discussion Nano-sized particles synthesized by FSP and submicron-sized particles synthesized by SD can be distinguished via microscopic analysis.In addition,the fine particles are evenly distributed around the coarse particles,having a porous structure that meets an expected cathode microstructure.Under the experimental conditions,the overall ohmic impedance and polarization impedance both increase and then decrease as the proportio

关 键 词：固体氧化物燃料电池 火焰喷雾热解法 喷雾干燥法 阴极 弛豫时间分布法 

分 类 号：TM911.4[电气工程—电力电子与电力传动] TB33[一般工业技术—材料科学与工程]