三聚氯氰催化N-苯基马来酰亚胺的合成  

Synthesis of N-phenylmaleimide Catalyzed by Cyanuric Chloride

作　　者：黄文楚 张海侠[1] 李林博 刘志鑫 张开旭 Huang Wenchu;Zhang Haixia;Li Linbo;Liu Zhixin;Zhang Kaixu(Jiamusi University,Jiamusi 154007,China)

机构地区：[1]佳木斯大学,黑龙江佳木斯154007

出　　处：《广东化工》2024年第11期35-37,共3页Guangdong Chemical Industry

摘　　要：本文对N-苯基马来酰亚胺(N-PMI)的合成工艺进行创新。以顺丁烯二酸酐和苯胺为原料,分别在乙酸乙酯、甲苯和氯苯中合成N-苯基马来酰胺酸(N-PMA);再以三聚氯氰和三乙胺为催化剂,在不同溶剂中制备N-PMI。改进后的工艺操作较为简单、所需原料试剂易得,为N-PMI的合成提供了一种新思路。In this paper,the synthesis process of N-phenylmaleimide(N-PMI)was innovated.N-phenylmaleamide acid(N-PMA)was synthesized from maleic anhydride and aniline in ethyl acetate,toluene and chlorobenzene,respectively;Then N-PMI was prepared in different solvents with cyanuric chloride and triethylamine as catalysts.The improved process is relatively simple and the required raw materials and reagents are easily available,which provides a new idea for the synthesis of N-PMI.

关 键 词：N-PMA N-PMI 合成 三聚氯氰 工艺创新 

分 类 号：TQ[化学工程]