Adsorption of Malachite Green Using Activated Carbon from Mangosteen Peel: Optimization Using Box-Behnken Design  

作　　者：Nabila Eka Yuningsih Latifa Ariani Suprapto Suprapto Ita Ulfin Harmami Harmami Hendro Juwono Yatim Lailun Ni’mah 

机构地区：[1]Department of Chemistry,Faculty of Science and Data Analytics,Institute Technology of Sepuluh Nopember,Surabaya,60111,Indonesia

出　　处：《Journal of Renewable Materials》2024年第5期981-992,共12页可再生材料杂志（英文）

摘　　要：In this research,activated carbon from mangosteen peel has been synthesized using sulfuric acid as an activator.The adsorption performance of the activated carbon was optimized using malachite green dye as absorbate.Mala-chite green dye waste is a toxic and non-biodegradable material that damages the environment.Optimization of adsorption processes was carried out using Response Surface Methodology(RSM)with a Box-Behnken Design(BBD).The synthesized activated carbon was characterized using FTIR and SEM instruments.The FTIR spectra confirmed the presence of a sulfonate group(-SO_(3)H)in the activated carbon,indicating that the activation pro-cess using sulfuric acid was successful.SEM characterization shows that activated carbon has porous morphology.Optimization was carried out for three adsorption parameters,namely contact time(20,60,and 120 min),adsor-bent mass(0.005,0.025,and 0.05 g),and initial concentration of malachite green solution(5,50,and 100 mg·L^(-1)).The concentration of the malachite green solution was determined using a UV-Vis spectrophotometer at the max-imum wavelength of malachite green,618 nm.The optimum of malachite green adsorption using mangosteen peel activated carbon was obtained at a contact time of 80 min,an adsorbent mass of 0.032 g,and malachite green initial concentration of 25 mg·L^(-1),with a maximum removal percentage and maximum adsorption capacity of 93.66%and 19.345 mg·g^(-1),respectively.

关 键 词：Response surface methodology DYES activated carbon experimental design 

分 类 号：O64[理学—物理化学]