多元复合改性Ag/SnO_(2)触点材料的内氧化法制备与电气性能研究  

Preparation and Electrical Life Performance of Multi-component Modified Ag/SnO_(2)Electrical Contact Materials by Internal Oxidation Method

作　　者：沈涛 穆成法 曹旭丹[1] 刘振武 李跃 陈林驰 陈晓 杨辉[1,3] Shen Tao;Mu Chengfa;Cao Xudan;Liu Zhenwu;Li Yue;Chen Linchi;Chen Xiao;Yang Hui(School of Materials Science and Engineering,Zhejiang University,Hangzhou 310027,China;Wenzhou Hongfeng Electrical Alloy Co.,Ltd,Wenzhou 325000,China;Wenzhou Research Institute of Zhejiang University,Wenzhou 325036,China)

机构地区：[1]浙江大学材料科学与工程学院,浙江杭州310027 [2]温州宏丰电工合金股份有限公司,浙江温州325000 [3]浙江大学温州研究院,浙江温州325036

出　　处：《稀有金属材料与工程》2024年第6期1632-1641,共10页Rare Metal Materials and Engineering

基　　金：浙江大学科技创新合作专项(2020ZD002)。

摘　　要：为探究掺杂组元类型及含量对多元复合改性Ag/SnO_(2)In_(2)O_(3)触点材料的内氧化法制备工艺、微观结构、显微硬度、温升、电寿命等电气性能的影响规律,采用中频熔炼-铸造工艺制备了改性AgSnIn合金,通过内氧化法制备了多元复合改性Ag/SnO_(2)In_(2)O_(3)触点材料。利用AC-4电寿命型式试验平台对触点材料进行温升、电寿命性能评价。结果表明,改性Ag/SnO_(2)In_(2)O_(3)材料的内氧化工艺优选参数为700℃/5 MPa/48 h。相比于Ni、Cu或Zn二元改性而言,Ni-Cu-Zn三元改性Ag Sn合金内部存在较大的微应变,相应的改性Ag/SnO_(2)In_(2)O_(3)材料的显微硬度随着In元素含量的降低呈先上升后急剧下降。由0.47%Ni、0.4%Cu、0.43%Zn和2.1%In(质量分数)组成的改性AgSnIn合金可实现完全内氧化,相应的改性Ag/SnO_(2)In_(2)O_(3)材料表现为最佳的显微硬度(1382.49 MPa)、最长服役寿命(28989次)和合适的温升(43.69 K),这归因于显微结构中存在较大的微应变(1.9×10^(-4))和起到强化效应的晶界组织。经分析发现,在特定的In含量2.1%~3.1%(质量分数),改性Ag/SnO_(2)触点材料的电寿命循环周期与显微硬度大小之间呈正相关性,这一结果将为Ag/SnO_(2)触点材料的配方设计与电寿命性能预测提供新思路。In order to explore the impact of the type and content of the modified components on the preparation process,microstructure,microhardness,temperature rise and electrical life of the modified Ag/SnO_(2)In_(2)O_(3)contact materials,the modified AgSnIn alloys were synthesized by medium-frequency smelting and casting process,and then the corresponding Ag/SnO_(2)In_(2)O_(3)contact materials were prepared by internal oxidation method.The AC-4 electrical life type testing platform was used to evaluate the temperature rise and electrical life performance of the materials.The results show that the optimum parameters of internal oxidation process of the modified Ag/SnO_(2)In_(2)O_(3)materials are 700℃/5 MPa/48 h.Compared with the binary modification of Ni,Cu or Zn,there exists larger micro-strain in the Ni-Cu-Zn ternary modified AgSnIn alloys,and the microhardness of the corresponding modified Ag/SnO_(2)In_(2)O_(3)material increases first and then decreases sharply with indium content decreasing.The modified AgSnIn alloy,composed of 0.47wt%Ni,0.4wt%Cu,0.43wt%Zn and 2.1wt%In,could achieve complete internal oxidation.The corresponding modified Ag/SnO_(2)In_(2)O_(3)material presents the optimum microhardness(1382.49 MPa),the longest cycle number(28989 operations)and an appropriate temperature rise(43.69 K),which is attributed to some larger micro-strain(1.9×10^(-4))and grain boundary structure with strengthening effect.The comparison analysis reveals a positive correlation has been established between the electric life cycle number and the microhardness of the modified Ag/SnO_(2)material within In element content range from 2.1wt%to 3.1wt%,which provides a new idea for the formulation design and electric life performance prediction of the Ag/SnO_(2)contact material.

关 键 词：Ag/SnO_(2)触点材料 内氧化 微应变 显微硬度 电寿命 

分 类 号：TM201.4[一般工业技术—材料科学与工程]