Recent progress on the functionalization of white phosphorus in China  

作　　者：Xinlei Huangfu Zhongzhen Wang Yu Chen Junnian Wei Wei Liu Wen-Xiong Zhang 

机构地区：[1]Beijing National Laboratory for Molecular Sciences(BNLMS),State Key Laboratory of Rare-Earth Materials Chemistry and Applications&Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China

出　　处：《National Science Review》2024年第6期301-313,共13页国家科学评论（英文版）

摘　　要：Direct synthesis of organophosphorus compounds from white phosphorus represents a significant butchallenging subject, especially in the context of ongoing efforts to comprehensively improve thephosphorus-derived chemical industry driven by sustainability and safety concerns. China is the world’slargest producer of white phosphorus, creating a significant demand for the green transformation of thiscrucial feedstock. This review provides an overview of advancements in white phosphorus activation byChinese research teams, focusing on the direct construction of P–C/N/O/S/M bonds from whitephosphorus. Additionally, we offer some insights into prospective directions for the activation andtransformation of white phosphorus in the future. This review paper aims to attract more researchers toengage in this area, stimulating follow-up exploration and fostering enduring advances.

关 键 词：white phosphorus organophosphorus compound ACTIVATION SELECTIVITY EFFICIENCY 

分 类 号：O627.51[理学—有机化学]