关于惰性含氟温室气体转化与利用的研究进展  

Recent Advances in Conversion and Use of Inert Fluorinated Greenhouse Gases

作　　者：邹震雷 李和寅 黄梦君 沈胤朴 刘继阳 王之兆 张为钢 王毅 潘毅 Zhenlei Zou;Heyin Li;Mengjun Huang;Yinpu Shen;Jiyang Liu;Zhizhao Wang;Weigang Zhang;Yi Wang;Yi Pan(AnHui Technology Research Center of Optoelectronic Technology Appliance,Biomimetic Energy Laboratory,School of Electrical Engineering,Tongling University,Tongling,Anhui 244000;State Key Laboratory of Coordination Chemistry,Jiangsu Key Laboratory of Advanced Organic Materials,Collaborative Innovation Center of Advanced Microstructures,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210033)

机构地区：[1]铜陵学院电气工程学院光电子应用安徽省工程技术研究中心仿生能源实验室,安徽铜陵244000 [2]南京大学化学化工学院配位化学国家重点实验室江苏省先进有机材料重点实验室,南京210033

出　　处：《有机化学》2024年第6期1831-1852,共22页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.21971107,22071101,22271147);铜陵学院基金(No.2023tlxyrc15)资助项目

摘　　要：过去的几十年里, 含氟气体因其特殊理化性质, 在人类社会中的应用几乎随处可见, 为人们的生产生活提供了诸多便利的同时, 正悄无声息地引起一系列环境危机. 长期研究表明含氟气体所造成的温室效应远高于其他温室气体, 人们不得不对含氟气体的使用进行重新评估. 为有效实现含氟气体的经济效益最大化及降低环境污染, 科学家们正努力开发含氟温室气体转化利用的新方法. 综述了近20年国内外化学家针对氟利昂、硫酰氟、三氟化氮和六氟化硫等惰性含氟温室气体转化与利用的最新研究成果.Over the past few decades, fluorinated greenhouse gases have been used almost everywhere in human society due to their special physical and chemical properties. In spite of the convenience they provide to peopleʼs production and life, they also cause many environmental problems. The relevant studies have shown that the release of fluorinated gases causes a more serious greenhouse effect than normal greenhouse gases. Therefore, the use of fluorinated gases must be reassessed. In order to maximize the economic benefits of fluorinated gases and reduce their environmental pollution, scientists all over the world are trying to develop new methods for the conversion and utilization of fluorinated greenhouse gases. we aim to provide an overview of the conversion and utilization of fluorinated greenhouse gases, such as freon, sulfuryl fluoride, nitrogen trifluoride and sulfur hexafluoride from 2000 to 2023.

关 键 词：惰性含氟温室气体 氟利昂 硫酰氟 三氟化氮 六氟化硫 

分 类 号：X701[环境科学与工程—环境工程]