含咔唑结构的小分子及聚合物催化二氧化碳转化研究进展  

Advances in Catalytic Conversion of CO_(2)with Carbazole-Based Molecules and Polymers

作　　者：姜晓琳 王超洋 武利园 李跃辉 Jiang Xiaolin;Wang Chaoyang;Wu Liyuan;Li Yuehui(Department of Pharmacy,Children’s Hospital of Soochow University,Suzhou,Jiangsu 215000;State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000;School of Environment and Energy Engineering,Beijing University of Civil Engineering and Architecture,Beijing 100044)

机构地区：[1]苏州大学附属儿童医院药剂科,江苏苏州215000 [2]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,兰州730000 [3]北京建筑大学环境与能源工程学院,北京100044

出　　处：《有机化学》2024年第5期1423-1444,共22页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.22072167,22001257);苏州大学附属儿童医院青年研究基金(No.2021QN05);苏州市“科教兴卫”青年科技(No.KJXW2022021)资助项目。

摘　　要：咔唑具有刚性平面结构和共轭π电子特征,表现出优异的电子传输性质.咔唑的N原子和芳环上容易进行化学修饰,以咔唑作为骨架或连接单元,人们方便地开发出结构多样的咔唑基配体和聚合物,并在催化和功能材料等研究领域中得到了广泛的应用.二氧化碳催化转化制备燃料和化学品,可以为实现双碳目标提供重要的技术支撑.综述了近年来咔唑基配体、咔唑基金属配合物及含咔唑结构的多相材料在催化CO_(2)相关反应方面的研究进展.通过介绍催化剂制备方法,归纳总结均相催化以及多相催化反应等内容,将为深入理解咔唑单元在催化中的重要作用,提升咔唑基材料的催化效率提供重要的参考信息.Carbazole moiety exhibits excellent electron transfer ability due to its rigid planar structure and large conjugate system.The N atom and aromatic ring of carbazole can be easily modified,and carbazole-based ligands and polymers have attracted significant amounts of interests in the fields of catalysis and material sciences.Important progress has been achieved in both homogeneous and heterogeneous catalysis promoted by catalysts containing carbazole as the backbone or linker.The catalytic conversion of carbon dioxide can provide an important technology support for realization of carbon neutrality goals.In this paper,the recent progresses on the use of carbazole-based ligands,carbazole-based complexes or carbazole-based heterogeneous materials in catalytic transformation of CO_(2)are reviewed,including the methods of catalyst preparation,the different types of reactions in homogeneous and heterogeneous catalysis.This review will provide systematic information for further understanding the important role of carbazole units in catalysis and designing more efficient carbazole-based materials.

关 键 词：咔唑结构 二氧化碳 均相催化 多相催化 电子传递 

分 类 号：X701[环境科学与工程—环境工程] O643.36[理学—物理化学]