金属催化醇胺N-烷基化反应的研究进展  

Advances in metal-catalyzed N-alkylation of amines with alcohols

作　　者：刘丽强 南军 王梓诚 王昊龙 蔡巷 段兴宇 LIU Li-qiang;NAN Jun;WANG Zi-cheng;WANG Hao-long;CAI Xiang;DUAN Xing-yu(CenerTech Tianjin Chemical Research and Design Institute Co.,Ltd.,Tianjin 300131,China)

机构地区：[1]中海油天津化工研究设计院有限公司,天津300131

出　　处：《现代化工》2024年第8期69-74,共6页Modern Chemical Industry

基　　金：中国海洋石油集团有限公司综合科研项目(CNOOC-KJ 145 FZDXM 00 TJY 001 TJY 2021)。

摘　　要：综述了近年来醇胺N-烷基化反应的最新研究进展,介绍了各种单金属及复合金属催化体系的反应特点,并对部分新型催化体系的预期机理进行了讨论,指出了该领域亟待解决的瓶颈以及未来发展方向。The latest research progress in the N-alkylation reaction between alcohols and amines in recent years is reviewed,the reaction characteristics over various single metal and composite metal catalytic systems are introduced,and the predicted mechanism of some new catalytic systems are analyzed.The bottlenecks that need to be solved in this field as well as the development directions in the future are proposed.

关 键 词：N-烷基化 醇 金属催化 胺 绿色化学 

分 类 号：O6-1[理学—化学] O622