孔隙特性对铝基非晶合金涂层腐蚀行为的影响  

Effect of pore characteristics on corrosion behavior of Al-based amorphous alloy coatings

作　　者：邱实 吕威闫 王琦[2] 王晓明 韩国峰 杨柏俊[2] QIU Shi;LYU Weiyan;WANG Qi;WANG Xiaoming;HAN Guofeng;YANG Baijun(Structure Corrosion Protection and Control of Aviation Science and Technology Key Laboratory,China Special Vehicle Research Institute,Jingmen 448035,Hubei,China;Shenyang National Laboratory for Materials Science,Institute of Metal Research,Chinese Academy of Sciences,Shenyang 110016,China;National Key Laboratory for Remanufacturing,Army Academy of Armored Forces,Beijing 100072,China)

机构地区：[1]中国特种飞行器研究所结构腐蚀防护与控制航空科技重点实验室,湖北荆门448035 [2]中国科学院金属研究所沈阳材料科学国家研究中心,沈阳110016 [3]陆军装甲兵学院装备再制造技术国防科技重点实验室,北京100072

出　　处：《材料工程》2024年第7期173-181,共9页Journal of Materials Engineering

基　　金：国家自然科学基金项目(52271157)。

摘　　要：采用超音速火焰喷涂(HVAF)技术制备1.36%高孔隙率(high porosity,HP)和0.86%低孔隙率(low porosity,LP)两种铝基非晶合金涂层,研究孔隙率对铝基非晶合金涂层腐蚀行为的影响。通过扫描电子显微镜(SEM),X射线衍射仪(XRD)并结合3D高分辨X射线衍射形貌(3D XRT)分析涂层孔隙率以及微观组织结构,利用电化学测试系统和接触角测量仪研究涂层的腐蚀行为,采用X射线光电子谱(XPS)分析两种涂层钝化膜成分。结果表明:LP涂层的自腐蚀电流密度(I_(corr))为3.0×10^(-6)A/cm^(2),点蚀电位(Epit)为-0.40 V,而HP涂层的I_(corr)为6.0×10^(-6)A/cm^(2),Epit为-0.47 V,LP涂层具有更好的耐局部点蚀能力;LP涂层的电荷转移电阻(Rct)约为HP涂层的2倍;LP涂层具有更大的接触角,疏水性更好;LP涂层形成的钝化膜中RE_(2)O_(3)的含量大于HP涂层,进一步说明LP涂层具有更优异的耐蚀性。High-velocity air-fuel spray(HVAF)technology was used to prepare two kinds of Al-based amorphous alloy coatings with high porosity(HP)of 1.36%and low porosity(LP)of 0.86%.The effects of porosities on the corrosion behavior of Al-based amorphous alloy coatings were studied.The porosities and microstructures of the coatings were analyzed by scanning electron microscope(SEM)and X-ray diffraction(XRD)combined with three-dimensional X-ray tomography(3D XRT).The corrosion properties of the coatings were studied by electrochemical testing system and contact angle measuring instrument.The passive film components of the two coatings were analyzed by X-ray photoelectron spectroscopy(XPS).The results show that the self-corrosion current density(I_(corr))and pitting potential(Epit)of the LP coatings are 3.0×10^(-6) A/cm^(2) and-0.40 V,respectively.The Icorr and Epit for HP coatings are 6.0×10^(-6) A/cm^(2) and-0.47 V,respectively,signifying that the LP coating has better resistance to the localized corrosion;the charge transfer resistance(R_(ct))of LP coatings is about twice than that of HP coating;the LP coating has a larger contact angle,which proves that LP coating has better hydrophobicity and stronger corrosion resistance;the contents of RE_(2)O_(3) in the passive film formed on the LP coating are larger,which further indicates that LP coating has better corrosion resistance.

关 键 词：非晶涂层 阻抗谱 腐蚀 润湿 疏水性 

分 类 号：TG178[金属学及工艺—金属表面处理]