热致变色智能窗户材料研究进展  

Advances in thermochromic smart window materials

作　　者：王定坤 陈国旗 付俊 Dingkun Wang;Guoqi Chen;Jun Fu(Guangdong Functional Biomaterial Engineering Technology Research Center,Key Laboratory of Polymer Composites and Functional Materials,Ministry of Education,School of Materials Science and Engineering,Sun Yat-sen University,Guangzhou 510006,China)

机构地区：[1]中山大学材料科学与工程学院,聚合物复合材料及功能材料教育部重点实验室,广东省功能生物材料工程技术研究中心,广州510006

出　　处：《科学通报》2024年第20期2898-2909,共12页Chinese Science Bulletin

基　　金：国家自然科学基金(22375225);中山大学2023年研究生培养质量提升资助经费(29000-11230011)资助。

摘　　要：窗户是建筑中的重要组成部分,也是室内外热交换的重要组件.频繁的热交换会增加室内能源消耗.节能型智能窗户可以调节室内外热交换,减少建筑能源消耗,符合低碳发展理念.热致变色智能窗户根据环境温度变化被动地调节太阳光辐射,无需额外输入能量,可以有效调节室内温度,在建筑节能领域具有潜在的应用价值.热致变色材料是在临界转变温度附近发生可逆相变的温度响应材料,相变前后伴随着显著的透射率/反射率变化,具有优异的太阳光调节能力,是构造热致变色智能窗的关键.本文重点介绍了VO_(2)、水凝胶、钙钛矿、离子液体和液晶5种代表性材料的热响应机理,系统地阐述了它们在智能窗户中的工作原理、最新研究进展以及仍需解决的科学问题,展望了热致变色智能窗户的发展方向.Thermochromic smart windows can intelligently regulate indoor solar radiation in response to surrounding temperature changes.This effectively reduces energy consumption in buildings and is a promising technology for building energy saving.Thermoresponsive materials,the integral components in thermochromic smart windows,undergo reversible phase changes near the critical transition temperature.In this review,we summarize thermoresponsive materials,including VO_(2),hydrogels,perovskites,ionic liquids,and liquid crystals.A critical review of the thermochromic mechanisms and recent progress made in these materials is presented.Furthermore,current challenges and developing-trends in thermoresponsive materials are also discussed.(1)VO_(2)is the most widely studied material for thermochromic smart windows due to its unique properties,as it undergoes a metal-to-insulator transition at a critical temperature of 68℃.Various methods have been proposed to enhance specific properties of VO_(2),such as optical properties and transition temperatures,including element doping,multilayer film structures,nanocomposite films,and nano-/microstructures.However,simultaneously enhancingτ_(c),ΔT_(sol)and T_(lum)remains a challenge for VO_(2).(2)Hydrogels are regarded as highly promising materials for thermochromic smart windows due to their reversible phase transition between hydrophilic and hydrophobic phases.Well-known thermochromic hydrogels include poly(Nisopropylacrylamide)(PNIPAm),hydroxypropyl cellulose(HPC),and poly(N-vinylcaprolactam)(PNVCL).However,thermochromic hydrogels often exhibit weak mechanical properties and undesirable freezing at cold temperatures,which need to be addressed in future research to facilitate their applications in smart windows.(3)Thermochromic perovskites have apparent solubility variations at different temperatures,accompanied by the shift of absorbance band gaps,leading to optical change from transparency to opaqueness.However,there are some problems that hinder the development of perovskites in th

关 键 词：热致变色 智能窗户 临界转变温度 可逆相变 建筑节能 

分 类 号：TU111.48[建筑科学—建筑理论]