高分子表面活性剂在不同洗涤剂中的应用性能  

China Surfactant Detergent&Cosmetics Application properties of a polymeric surfactant in different detergents

作　　者：严羽欢 潘鹤潮 鲍红洁 赵建红 何一波[3] Yuhuan Yan;Hechao Pan;Hongjie Bao;Jianhong Zhao;Yibo He(HeChuang(Guangzhou)Technology Research Co.,Ltd.,Guangzhou,Guangdong 510006,China;Institute of Green Commodity Innovation,Guangdong University of Technology,Guangzhou,Guangdong 510006,China;Key Laboratory of Green Cleaning Technology&Detergent of Zhejiang Province,Nice Group Co.,Ltd.,Lishui,Zhejiang 323000,China)

机构地区：[1]合创(广州)科技研究有限公司,广东广州510006 [2]广东工业大学绿色日用品创新研究院,广东广州510006 [3]纳爱斯集团有限公司浙江省绿色清洁技术及洗涤用品重点实验室,浙江丽水323000

出　　处：《日用化学工业（中英文）》2024年第8期930-938,共9页China Surfactant Detergent & Cosmetics

基　　金：浙江省绿色清洁技术及洗涤用品重点实验室开放课题(Q202207)。

摘　　要：分别利用凝胶色谱仪、表面张力仪和激光粒度仪表征了聚醚-聚丙烯酸/酯高分子表面活性剂HS-PA的分子量、表面张力以及胶束聚集体的粒径分布。并考察了HS-PA在分别以LAS/AES/AEO_(9)为主表面活性剂的非结构型/结构型洗涤剂中的增稠性能、去污性能、液晶形态、悬浮性能以及流变行为。性能表征结果表明:HS-PA的重均分子量为4244,临界胶束浓度为3×10^(-7)mol/L,平衡表面张力为42.06 mN/m;当HS-PA分别与LAS、AES、AEO_(9)形成混合胶束时,聚集体的平均粒径增大;在非结构型洗涤剂中的应用测试结果表明:HS-PA对LAS/AES/AEO_(9)为主表面活性剂的配方均有提升黏度的作用,同时有利于改善洗涤剂在JB03皮脂污布上的去污力;在结构型洗涤剂中的应用测试结果说明:HS-PA将有助于LAS/AES/AEO_(9)体系形成球形层状液晶,且HS-PA用量越多,AES体系的液晶数量越多;离心结果表明,含HS-PA的结构型洗涤剂具有稳定悬浮微胶囊的能力;经旋转流变仪测定,HS-PA可提高LAS配方体系的屈服应力。The molecular weight,surface tension,and the particle size distribution of micellar aggregates of a polyetherpolyacrylate polymeric surfactant,HS-PA,were characterized on gel permeation chromatograph,surface tension meter,and laser particle size analyzer,respectively.The thickening properties,detergency,liquid crystal morphology,suspension properties,and rheological behaviors of HS-PA in unstructured/structured detergents with LAS/AES/AEO_(9) as the main surfactants,respectively,were also investigated.The characterization results showed that,the weight-average molecular weight of HS-PA was 4244,the critical micelle concentration was 3×10^(-7)mol/L,and the equilibrium surface tension was 42.06 mN/m;the average particle size of aggregates was increased when LAS,AES and AEO_(9) formed mixed micelles with HS-PA,respectively.The application test in unstructured detergents showed that,HS-PA had viscosityenhancing effects on all the LAS/AES/AEO_(9)-based systems,and meanwhile it was beneficial to the improvement of the detergency to sebum.The application test in structured detergents showed that,HS-PA would help the formation of lamellar liquid crystals in the LAS/AES/AEO_(9) systems,and the more HS-PA used,the more the liquid crystals in the AES system;the centrifugal separation results showed that the structured detergents containing HS-PA had the ability to stabilize the suspension of microcapsules;HS-PA could increase the yield stress of the LAS formulation system as determined by rotational rheometer.

关 键 词：高分子表面活性剂 结构型洗涤剂 非结构型洗涤剂 

分 类 号：TQ423[化学工程]