糠醇选择性加氢制备1,2-戊二醇  

Selective Hydrogenation of Furfuryl Alcohol to 1,2-Pentanediol

作　　者：罗文星 汪永军 向明林 周冬京 邱长玖 LUO Wenxing;WANG Yongjun;XIANG Minglin;ZHOU Dongjing;QIU Changjiu(Hunan Changlian New Material Technology Co.,Ltd.,Yueyang Hunan 414012,China)

机构地区：[1]湖南长炼新材料科技股份公司,湖南岳阳414012

出　　处：《当代化工》2024年第7期1654-1658,共5页Contemporary Chemical Industry

摘　　要：糠醇选择性加氢制备1,2-戊二醇是一种复杂的化学反应,存在选择性差、副产多、成本高等问题。合成了一种新型Cu-CLXC催化剂,在固定床模式及温和条件下(反应温度160℃、反应压力5 MPa、空速0.3 h-1)对糠醇加氢表现出优异的催化活性,原料转化率>99.9%,1,2-戊二醇选择性>60.0%,并且该催化剂连续运行2 000 h后活性未见下降趋势,催化活性及稳定性远高于现有报道的催化剂水平。Selective hydrogenation of furfuryl alcohol to 1,2-pentanediol is a complex reaction,which has many problems such as poor selectivity,high by-product and high cost.A new Cu-CLXC catalyst was synthesized and showed excellent catalytic activity for hydrogenation of furfuryl alcohol in a fixed bed reactor under mild conditions(reaction temperature 160 ℃,reaction pressure 5 MPa,airspeed 0.3 h-1),the conversion of raw materials was > 99.9% and the selectivity of 1,2-pentanediol was > 60.0%,the activity and stability of the catalyst were higher than that of the reported catalysts after running for 2 000 h.

关 键 词：1 2-戊二醇 固定床 活性 生产 稳定性 

分 类 号：TQ016[化学工程]