不同粒级铜尾矿对CaO-MgO-Al_(2)O_(3)-SiO_(2)微晶玻璃析晶性能的影响  

Effect of Copper Tailings with Different Sizes on Crystallization Properties of CaO-MgO-Al_(2)O_(3)-SiO_(2)Glass-ceramics

作　　者：施麟芸 徐玉华[3] 匡敬忠[1] 魏琦 SHI Linyun;XU Yuhua;KUANG Jingzhong;WEI Qi(School of Resources and Environmental Engineering,Jiangxi University of Science and Technology,Ganzhou 341000,China;Jiangxi Building Materials Industry Research and Design Institute,Nanchang 330001,China;School of Materials Science and Engineering,Nanchang University,Nanchang 330001,China)

机构地区：[1]江西理工大学资源与环境工程学院,江西赣州341000 [2]江西省建筑材料工业科学研究设计院,江西南昌330001 [3]南昌大学材料科学与工程学院,江西南昌330001

出　　处：《材料科学与工程学报》2024年第3期387-393,共7页Journal of Materials Science and Engineering

基　　金：国家重点研发计划资助项目(2018YFC1903400,2018YFC1903402)。

摘　　要：采用不同粒级铜尾矿通过熔融法制备CaO-MgO-Al_(2)O_(3)-SiO_(2)(CMAS)微晶玻璃,通过差示扫描量热仪(DSC)、X射线衍射仪(XRD)和扫描电子显微镜-能谱仪(SEM-EDS)等测试方法分析了不同细度的铜尾矿对微晶玻璃析晶行为的影响,并借助JMA方程拟合了不同粒级铜尾矿微晶玻璃的析晶动力学行为。研究表明,不同粒级组成的铜尾矿中含铁矿物的种类和价态影响微晶玻璃的析晶行为。铜尾矿中的铁氧化物来源于原生矿物,如菱铁矿、硫铁矿、磁铁矿等含铁矿物多为Fe^(2+),不具备成核诱导作用且促进了玻璃体和中间体的形成,而外加氧化铁为Fe^(3+),具有较好的成核诱导作用并促进了高铁辉石晶相的析出,从而提高了微晶玻璃的各项性能。Copper tailings with various particle sizes were melted to prepare CaO-MgO-Al_(2)O_(3)-SiO_(2)(CMAS)glass ceramics.DSC,XRD,and SEM-EDS were used to examine the crystallization properties of glass ceramics.JMA equation was used to fit the crystallization kinetics features of glass ceramics,which were made from copper tailings with various particles.The various kinds and valence states of iron-bearing minerals in copper tailings have distinct effects on the crystallization of glass-ceramics.Fe^(2+)-enriched minerals such as siderite,pyrite,and magnetite in copper tailings have no nucleation induction and promote the vitreous and intermediate phases.Therefore,the additional iron oxide of Fe^(3+)has a stronger nucleation induction,and enhances the precipitation of the ferro-pyroxene crystal phase,increasing the characteristics of glass ceramics.

关 键 词：铜尾矿 粒级 微晶玻璃 晶核剂 含铁矿物 析晶性能 析晶动力学 

分 类 号：TD926.4[矿业工程—选矿]