光功能杂化凝胶玻璃器件研究进展  

Research Progress on Optical Functional Hybrid Gel Glass Devices

作　　者：黄招娣 唐小燕 杨清芳 王晶京 谢政 HUANG Zhaodi;TANG Xiaoyan;YANG Qingfang;WANG Jingjing;XIE Zheng(School of Chemistry and Chemical Engineering,University of Jinan,Jinan 250022,China)

机构地区：[1]济南大学,化学化工学院,济南250022

出　　处：《硅酸盐学报》2024年第8期2722-2737,共16页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(20904063,21274002,51561145004,21875267,22275202);济南大学2023年学科交叉会聚建设项目(XKJC-202312)。

摘　　要：光功能杂化凝胶玻璃是一类具有广泛应用潜力的新型杂化材料与器件,集成融合了凝胶玻璃和光功能材料的特性和优势。本文主要综述了多种玻璃基质为载体的光功能杂化玻璃器件,尤其是凝胶玻璃基质作为光学材料载体的杂化凝胶玻璃器件的最新研究进展,系统介绍了非线性光学激光防护/调制杂化玻璃器件和发光/转换杂化玻璃器件2大类。最后,结合当前研究进展,展望了光功能杂化凝胶玻璃未来发展过程中可能面临的问题和挑战。本综述将有望为光功能杂化材料与玻璃的设计制备、性能优化以及器件制备和应用提供一定的启示,推动光功能杂化凝胶玻璃器件的发展。Optical functional hybrid gel glass is a new type of device material with wide potential application.It integrates the characteristics and advantages of gel glasses and optical functional materials,has excellent optical,electrical and chemical properties,and has been widely used in energy,optoelectronics,sensors and other fields.It has become very appropriate device materials in the field of optics and other fields.It is mainly composed of transparent hybrid material glass and optical functional hybrid gel glass,with high refractive index and low scattering,mechanical strength and heat resistance,withstand high temperature and extreme environment,not easy to produce deformation or rupture.Researchers continue to explore and innovate by changing the composition,structure and preparation process of materials.By precisely controlling the microstructure and the distribution of functional substances of the hybrid gel glasses,the performance of optics,electricity and thermology can be effectively regulated.This paper reviews a variety of optical functional hybrid glass devices supported by glass matrices,especially the latest research progress of hybrid gel glass devices supported by gel glass matrices,and mainly systematically introduce two types of glass devices:nonlinear optical laser protection/modulation and luminescence/conversion hybrid glass devices.The most common preparation methods for optical functional hybrid glass devices include in-situ growth,surface coating and direct doping,etc.These methods have their advantages and disadvantages.At present,the combination of glass matrices with a variety of nanomaterials/structures is limited to in-situ growth and surface coating,and it is difficult to achieve high concentration uniform doping of different kinds of functional materials.As far as the glass itself is concerned,inorganic glass has very high physicochemical and thermal stability and excellent optical properties,but the traditional melting method requires high temperature processing,and organic and carbo

关 键 词：光功能杂化 凝胶玻璃 非线性光学 发光转换 光学器件 

分 类 号：TQ171.1[化学工程—玻璃工业]