分子筛在催化脱硫中的研究进展  

Current state of molecular sieves in catalytic desulfurization

作　　者：张乐 黎玉婷 胡海峰 吕新虎 段林海 高雄厚[3] Zhang Le;Li Yuting;Hu Haifeng;LüXinhu;Duan Linhai;Gao Xionghou(School of Chemical Engineering,Guangdong University of Petrochemical Technology,Maoming 525000,Guangdong,China;Guangdong Key Laboratory of Inferior Crude Oil Processing,Guangdong University of Petrochemical Technology,Maoming 525000,Guangdong,China;Lanzhou Petrochemical Branch,China Petroleum and Natural Gas Co.,Ltd.,Lanzhou 730060,Gansu,China;Liaocheng Product Quality Supervision and Inspection Institute,Liaocheng 252022,Shandong,China)

机构地区：[1]广东石油化工学院化学工程学院,广东茂名525000 [2]广东石油化工学院广东省劣质油加工重点实验室,广东茂名525000 [3]中国石油天然气股份有限公司兰州石化分公司,甘肃兰州525000 [4]聊城市产品质量监督检验所,山东聊城252022

出　　处：《工业催化》2024年第8期1-8,共8页Industrial Catalysis

基　　金：广东省教学质量与教学改革工程项目(粤教高函[2023]4号213);广东省自然科学基金项目(2021A1515010502);广东省普通高校特色创新项目(2021KTSCX077);茂名绿色化工研究院“扬帆计划”应用创新项目(MMGCIRI-2022YFJH-Y-054);茂名市科技计划项目(2023021);广东石油化工学院人才引进项目(2020RC039)。

摘　　要：液体燃料(柴油和汽油)中存在的含硫化合物造成的空气污染,已成为当前社会各界关注的热点,绿色燃料对可持续发展和清洁环境至关重要。有效、完全地脱除燃料油中的含硫化合物是制备新型催化脱硫催化剂的技术关键。介绍分子筛在催化脱硫领域中的应用与研究,对现有主要的分子筛催化脱硫技术进行总结和分析,着重讨论分子筛在脱硫过程中的作用机制,阐述分子筛催化脱硫在石油加工领域中的应用现状,并对其发展前景进行展望。The air pollution caused by sulfur-containing compounds in liquid fuels(especially diesel and gasoline)has become a hot topic of concern in all walks of life.Green fuel is very important for sustainable development and clean environment.Effective and complete removal of sulfur compounds from fuel oil is the technical key to prepare a new catalytic desulfurization catalyst.In this paper,the application and research of molecular sieve in the field of catalytic desulfurization are reviewed,the existing main molecular sieve catalytic desulfurization technologies are summarized and analyzed,the mechanism of zeolites in desulfurization process is emphatically discussed,the application status of molecular sieve catalytic desulfurization in petroleum processing field is expounded,and its development prospect is prospected.

关 键 词：石油化学工程 脱硫 吸附 氧化 烷基化 

分 类 号：TQ426.95[化学工程] TE624.9[石油与天然气工程—油气加工工程]