聚合物-微生物杂合体的构建及催化应用  

Construction of Polymer-Microorganism Hybrids for Catalysis

作　　者：邹雨泰 王文硕 刘健 Yutai Zou;Wenshuo Wang;Jian Liu(College of Materials Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042,China;Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy,Qingdao New Energy Shandong Laboratory,Qingdao Institute of Bioenergy and Bioprocess,Chinese Academy of Sciences,Qingdao 266101,China)

机构地区：[1]青岛科技大学材料科学与工程学院,青岛266042 [2]太阳能光电转化与利用重点实验室,青岛新能源山东省实验室,中国科学院青岛生物能源与过程研究所,青岛266101

出　　处：《化学进展》2024年第6期815-826,共12页Progress in Chemistry

基　　金：国家自然科学基金项目(No.22175104,22205253);山东省自然科学基金项目(No.ZR2019ZD47);山东省优秀青年科学基金项目(No.2023HWYQ-105);泰山学者计划资助。

摘　　要：设计材料-微生物杂合体系,利用太阳能等可再生能源进行绿色生物合成,有望为人类社会提供解决全球能源短缺和环境危机的可行方案。将人工材料优异的物理化学特性与微生物的生物合成功能进行耦合,构建杂合体系的研究在近年来受到了广泛关注。聚合物材料因其功能多样、可设计性强、生物兼容性好等特点被广泛应用于构建材料-微生物杂合体,在生物能源领域展现出广阔的应用前景。本文从聚合物材料的功能特点出发,系统总结了不同类型的聚合物-微生物杂合体,并论述了聚合物材料通过增强光能利用、加速电子传递、稳定生物活性等机制对杂合体催化性能的强化。最后,对聚合物-微生物杂合体系面临的挑战和未来发展前景进行展望。The design and development of material-microorganism hybrid systems that can use solar energy for green biosynthesis is expected to provide human society with a viable solution for addressing the global energy shortage and environmental crisis.In recent years,the construction of hybrid systems by coupling excellent physical and chemical features of artificial materials with the biosynthetic function of microorganisms has received extensive attention.Polymeric materials,due to versatile functions,excellent designability and good biocompatibility,have been widely used to construct material-microorganism hybrid systems,and have shown broad application prospects in the field of bioenergy.Based on the functional features of polymeric materials,this paper systematically summarizes different types of polymer-microorganism biohybrid systems,and discusses the augmentation of their catalytic performance by enhancing light utilization,accelerating electron transfer,and stabilizing biological activity.Finally,the challenges and future development of polymer-microorganism hybrid systems are discussed.

关 键 词：聚合物 生物杂合 生物催化 细胞表面工程 半人工光合作用 

分 类 号：O631[理学—高分子化学] O643.3[理学—化学]