聚丙烯酰胺电解质/锌负极一体化结构构筑与性能的综合实验设计  

Construction of Polyacrylamide Electrolyte/Zinc Anode Integrated Structure:Comprehensive Experimental Design for Majors of Chemical Materials

作　　者：温祖龙 李坚 梁业如 张淑婷 曹巧英 WEN Zu-long;LI Jian;LIANG Ye-ru;ZHANG Shu-ting;CAO Qiao-ying(College of Meterials and Energy,South China Agricultural University,Guangdong Guangzhou 510642,China)

机构地区：[1]华南农业大学材料与能源学院,广东广州510642

出　　处：《广州化工》2024年第13期150-153,161,共5页GuangZhou Chemical Industry

基　　金：2021年度校级教育教学改革与研究项目(No:JG21110、4900/K22193)。

摘　　要：结合材料相关专业的实践教学目标及学科前沿方向,设计了“锌离子电池负极材料的界面改性及性能表征”综合性实验。以硅烷偶联剂KH570改性锌箔表面,并与丙烯酰胺原位聚合,构筑出聚丙烯酰胺电解质/锌负极一体化结构。在此基础上,组装成锌离子电池并测试其电化学性能,重点探讨了界面改性对降低锌电极与电解质界面电阻的影响。实验内容体现了多学科的交叉融合,具有前沿性和开放性,有利于激发学生的科研兴趣,提升学生的创新思维和综合实验技能。Combined with the practical teaching objectives and cutting-edge direction of materials related majors,a comprehensive experiment of“interface modification and performance characterization of negative electrode materials for zinc ion batteries”was designed.The surface of zinc foil was modified with silane coupling agent KH570 and polymerized with acrylamide in situ to construct the integrated structure of polyacrylamide electrolyte/zinc anode.On this basis,the zinc ion battery was assembled and its electrochemical performance was tested.The effect of interface modification on reducing the interfacial resistance between zinc electrode and electrolyte was discussed.The experimental content reflected the cross integration of multiple disciplines,was cutting-edge and open,and conducive to stimulate students'interest in scientific research and improve students'innovative thinking and comprehensive experimental skills.

关 键 词：聚丙烯酰胺电解质 锌负极改性 低界面电阻 综合性实验设计 

分 类 号：TM911.3[电气工程—电力电子与电力传动]