LLDPE/POE中BN的分散结构对复合材料导热性能的影响  

Dispersion Structure of BN in LLDPE/POE Blends and Its Influences on Thermally Conductivity of Composites

作　　者：曲琦 潘林 梁斌 韩志东[1,3] QU Qi;PAN Lin;LIANG Bin;HAN Zhi-dong(School of Materials Science and Chemical Engineering,Harbin University of Science and Technology,Harbin 150040,China;Zhongtian Technology Industrial Wire&Cable System Co.,Ltd.,Nantong 226010,China;Key Laboratory of Engineering Dielectrics and Its Application,Ministry of Education,Harbin University of Science and Technology,Harbin 150080,China)

机构地区：[1]哈尔滨理工大学材料科学与化学工程学院,黑龙江哈尔滨150040 [2]中天科技装备电缆有限公司,江苏南通226010 [3]哈尔滨理工大学工程电介质及其应用教育部重点实验室,黑龙江哈尔滨150080

出　　处：《塑料科技》2024年第7期69-74,共6页Plastics Science and Technology

基　　金：黑龙江省自然基金重点资助项目(ZD2020E007)。

摘　　要：以线型低密度聚乙烯(LLDPE)和聚烯烃弹性(POE)为聚烯烃材料,以氮化硼(BN)为导热填料,采用熔融共混热压法制备LLDPE/POE/BN导热复合材料,研究工艺方法对BN分散结构的影响,探讨复合材料结构与导热性能的关系,并结合有限元模拟预测了复合材料的导热系数和温度场的变化。结果表明:通过3种工艺方法获得了具有不同BN分散结构的复合材料。BN在LLDPE相中分散形成的共连续结构复合材料具有优异的导热性能。BN质量分数为40%和50%时,复合材料的导热系数分别为0.72 W/(m·K)和0.91 W/(m·K)。基于BN的分散结构构筑了复合材料的结构模型,成功预测了复合材料的导热系数,揭示了共连续结构的复合材料表现出更好的传热行为。Using linear low-density polyethylene(LLDPE) and polyolefin elastomer(POE) as polyolefin materials and boron nitride(BN) as thermal conductivity filler,the LLDPE/POE/BN thermal conductivity composites was prepared by melt blending hot pressing method.The influence of the process on the dispersion structure of BN was studied,and the relationship between the structure and thermal conductivity of the composites was discussed.The thermal conductivity and temperature field of the composites were predicted by finite element simulation.The results show that the composites with different BN dispersion structures are obtained by three processes.The cocontinuous structure composites formed by BN dispersed in LLDPE phase has excellent thermal conductivity.When the mass fraction of BN is 40% and 50%,the thermal conductivity of the composites is 0.72 W/(m·K) and 0.91 W/(m·K),respectively.Based on the dispersion structure of BN,the structure model of the composites was constructed,the thermal conductivity of the composites was predicted successfully,and the better heat transfer behavior of the composites was revealed.

关 键 词：聚烯烃 氮化硼 导热系数 有限元模拟 

分 类 号：TB332[一般工业技术—材料科学与工程] TQ325.12[化学工程—合成树脂塑料工业]