加氢沥青的制备及其热聚合动力学研究  

Study on preparation and thermal polymerization kinetics of hydrogenated pitch

作　　者：高欣然 张广元 杨金连 陈猛 宋德辉 王坤 GAO Xinran;ZHANG Guangyuan;YANG Jinlian;CHEN Meng;SONG Dehui;WANG Kun(School of Civil Engineering,University of Science and Technology Liaoning,Anshan 114051,China;School of Chemical Engineering,University of Science and Technology Liaoning,Anshan 114051,China;Sinosteel Anshan Research Institute of Thermo-Energy Co.,Ltd.,Anshan 114044,China)

机构地区：[1]辽宁科技大学土木工程学院,辽宁鞍山114051 [2]辽宁科技大学化学工程学院,辽宁鞍山114051 [3]中钢集团鞍山热能研究院有限公司,辽宁鞍山114044

出　　处：《辽宁科技大学学报》2024年第3期190-196,共7页Journal of University of Science and Technology Liaoning

基　　金：辽宁省教育厅项目(JYTZD2023093,LJKQZ2021126);辽宁科技大学大学生创新创业训练计划。

摘　　要：以四氢萘为添加剂,考察不同添加量制备的加氢沥青的化学组成和结构变化规律。采用XRD和红外光谱分析沥青组成与结构的演变规律,使用连串反应模型计算反应动力学常数。结果表明,四氢萘有较好的供氢作用,添加量质量分数为50%时,沥青的氢原子与碳原子物质的量之比由0.35增加至0.80。加氢沥青中存在大量的环烷烃或脂肪支链,能够减缓液相炭化反应中稠环芳烃的过度聚合,TI-QS组分向QI组分转变的反应速率由0.061下降至0.035,有利于体系黏度的缓慢增加,从而形成广域结构的中间相沥青。Tetralin was used as an additive to investigate the chemical composition and structural change law of hydrogenated pitches prepared with different additive amounts.The composition and structural change law were further investigated by XRD and FT-IR.The reaction kinetics was calculated using a chain reaction model.The results revealed that tetralin is a good hydrogen donor.The hydrogen/carbon ratio of the pitches increased from 0.35 to 0.80 with the 50%additive mass fraction.Furthermore,the presence of large amounts of naphthenic structures or alkyl chains in the hydrogenated pitch hindered the overpolymerization of thick cyclic aromatic hydrocarbon during the liquid-phase carbonation reaction.The conversion rate of the TI-QS component to the QI component(k2)decreased from 0.061 to 0.035,which was conducive to a slow increase of system viscosity,resulting in the formation of intermediate-phase asphaltenes with a wide-area structure.

关 键 词：煤焦油沥青 加氢 化学组成 动力学 

分 类 号：TQ522.65[化学工程—煤化学工程]