Brønsted-acid sites induced photocatalytic cracking of low-polarity polyethylene plastics  

作　　者：Qianyou Wen Quan Zhang Zhengzheng Liu Huining Wang Shuya Hao Fan Zhang Lijuan Zhang Qing Han Gengfeng Zheng 

机构地区：[1]Laboratory of Advanced Materials,Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials,Fudan University,Shanghai 200438,China

出　　处：《Journal of Energy Chemistry》2024年第9期509-515,共7页能源化学（英文版）

基　　金：the following funding agencies for supporting this work: the National Natural Science Foundation of China (22025502, U23A20552, 22379026, 22222901, 22175022);the Natural Science Foundation of Shanghai (23ZR1407000);the Science and Technology Commission of Shanghai Municipality (21DZ1206800)

摘　　要：Polyolefins such as polyethylene(PE)are one of the largest-scale synthetic plastics and play a key role in modern society.However,polyethylene is extremely inert to chemical recycling owing to its lack of chemical functionality and low polarity,making it one of the most challenging environmental hazards globally.Herein,we developed a phosphorylated CeO_(2)catalyst by an organophosphate precursor and featured efficient photocatalysis of low-density polyethylene(LDPE)without the acid or alkaline pre-treatment.Compared to pristine CeO_(2),the surface phosphorylation allows to introduce Brønsted acid sites,which facilitate to form carbonium ions on LDPE via protonation.In addition,the suitable band structure of the phosphorylated CeO_(2)catalyst enables efficient photoabsorption and generates reactive oxygen species,leading to the C–C bond cleavage of LDPE.As a result,the phosphorylated CeO_(2)catalyst exhibited an outstanding carbon conversion rate of>94%after 48 h of photocatalysis under 50 mW/cm^(2)of simulated sunlight,with a high CO_(2)product selectivity of>99%.Furthermore,the PE microparticles with sizes larger than 10μm released from LDPE plastic wrap were directly and completely degraded by photocatalysis within 12 h,suggesting an attractive and environmentally benign strategy of utilizing solar energy-based photocatalysis for reducing potential hazards of LDPE plastic trashes.

关 键 词：Photocatalytic cracking POLYETHYLENE Surface phosphorylation Bronsted-acid site Carbon conversion 

分 类 号：TQ325.12[化学工程—合成树脂塑料工业] O643.36[理学—物理化学] O644.1[理学—化学]