MOFs材料在CO_(x)加氢制醇反应中的研究进展  

Research Progress in the Application of MOFs Materials in CO_(x)Hydrogenation to Alcohols

作　　者：王诗怡 罗明生[1,2] 张子扬 WANG Shi-yi;LUO Ming-sheng;ZHANG Zi-yang(School of New Materials and Chemical Engineering,Beiling Institute of Petrochemical Technology,Beijing 102617,China;Beijing Key Laboratory of Fuel Cleaning and Efficient Catalytic Emission Reduction Technology,Beijing 102617,China)

机构地区：[1]北京石油化工学院新材料与化工学院,北京102617 [2]燃料清洁化及高效催化减排技术北京市重点实验室,北京102617

出　　处：《分子催化（中英文）》2024年第4期386-398,共13页Journal of Molecular Catalysis(China)

摘　　要：传统燃料燃烧过程中排放的CO_(2)/CO会导致环境的日益恶化,通过热催化将CO_(2)/CO还原成高附加值的醇类是应对和解决环境恶化问题的有效途径之一.然而,要得到收率和选择性高的产物,需要设计高效的催化剂来提高CO_(2)/CO加氢的催化活性.MOFs材料由于其独特的物理化学性质和高度可调性等特点,在加氢催化领域受到了人们的广泛关注.因此,我们系统地阐述了MOFs材料在碳氧化物CO_(x)加氢制醇反应中的研究进展,总结了碳氧化物加氢制醇的部分反应机理,同时对MOFs材料应用于CO_(x)加氢反应的性能表现和合成方法进行了初步探讨.The escalating emissions of CO_(2)/CO during conventional fuel combustion have exacerbated environmental deterioration.A promising avenue to mitigate this environmental challenge is catalytic reduction of CO_(2)/CO into high-value alcohols through thermal catalysis.However,achieving high yields and selectivity necessitates designing efficient catalysts to augment CO_(2)/CO hydrogenation catalytic activity.MOFs materials have garnered substantial attention in hydrogenation catalysis owing to their unique physical and chemical properties and high tunability.Hence,we comprehensively review the research advancements of MOFs materials in CO_(x)hydrogenation for alcohol synthesis,elucidate partial reaction mechanisms of carbon O_(x)ide hydrogenation for alcohol synthesis,and provide preliminary insights into the performance and synthesis methods of MOFs materials employed in CO_(x)hydrogenation reactions.

关 键 词：合成气转化 CO_(x)加氢 低碳醇 MOFS 

分 类 号：O643.32[理学—物理化学]