金属有机骨架材料催化转化CO_(2)应用研究进展  

Research Progress on Conversion and Utilization of CO_(2) Catalyzed by MOF

作　　者：李佳 苗萌 冯婧 潘洪志 LI Jia;MIAO Meng;FENG Jing;PAN Hong-zhi(The College of Medical Technology,Shanghai University of Medicine&Health Sciences,Shanghai 201318,China;Collaborative Research Center,Shanghai University of Medicine&Health Sciences,Shanghai 201318,China)

机构地区：[1]上海健康医学院医学技术学院,上海201318 [2]上海健康医学院协同科研中心,上海201318

出　　处：《化学试剂》2024年第9期23-31,共9页Chemical Reagents

基　　金：国家自然科学基金项目(82273687,81973097);上海健康医学院师资人才百人库产学研践习项目(A3-0200-24-311007)。

摘　　要：二氧化碳(CO_(2))排放量不断增加,加剧了环境问题,二氧化碳转化和利用成为实现“碳中和”化学工业目标的关键所在。与CO_(2)捕获和存储技术相比,将CO_(2)转化为有价值的化学品或能源燃料被视为解决能源与环境问题的有效策略。催化剂在这一领域扮演关键角色。近年来,金属有机骨架材料(MOFs)作为一种新型催化剂,具有可调控的结构、高度可控的孔隙结构以及多活性位点协同作用等独特特点,在CO_(2)催化转化领域取得显著进展。总结了MOFs催化剂在CO_(2)环加成转化、加氢、还原成CO等领域的研究进展,突出了MOFs催化剂在CO_(2)催化转化领域的潜力和应用前景。The increasing emissions of carbon dioxide have exacerbated environmental issues,and the conversion and utilization of carbon dioxide have become a crucial aspect in achieving the“carbon neutrality”goal in the chemical industry.Compared with carbon capture and storage technologies,converting carbon dioxide into valuable chemicals or energy fuels is considered an effective strategy for solving energy and environmental problems.Catalysts play a key role in this field.In recent years,metal-organic framework(MOF)materials,which possess tunable structures,highly controllable pore structures,and unique characteristics such as synergistic effects from multiple active sites,have made significant progress in the field of CO_(2)catalytic conversion.The research progress of MOF catalysts in the areas of CO_(2)cycloaddition,hydrogenation,and reduction to CO was summarized,highlighting the potential and application prospects of MOF catalysts in the realm of CO_(2)catalytic conversion.

关 键 词：金属有机骨架材料(MOFs) CO_(2) 催化 转化 环加成 加氢 

分 类 号：X511[环境科学与工程—环境工程]