基于载氮体氢化与再生的化学链合成氨技术及展望  

TECHNOLOGY AND PROSPECT OF CHEMICAL LOOPING AMMONIA SYNTHESIS BASED ON HYDROGENATION AND REGENERATION OF NITROGEN CARRIERS

作　　者：王思珺 巩峰 付恩康 肖睿 Wang Sijun;Gong Feng;Fu Enkang;Xiao Rui(Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education,School of Energy and Environment,Southeast University,Nanjing 210096,China)

机构地区：[1]东南大学能源与环境学院,能源热转换及其过程测控教育部重点实验室,南京210096

出　　处：《太阳能学报》2024年第8期44-53,共10页Acta Energiae Solaris Sinica

基　　金：国家自然科学基金(52076045)。

摘　　要：综述基于载氮体氢化与再生的化学链合成氨研究现状,讨论制约化学链速率的关键因素,并提出调控和增强载氮体性能的策略。总结载氮体的制备方法,从应用的角度评估载氮体性能调控的目标,以期为载氮体介导的化学链合成氨研究提供指导,促进基础研究向工业技术的转化。The present article reviews the advances of chemical looping ammonia synthesis(CLAS)based on hydrogenation and regeneration of nitrogen carriers.The key factors in challenging the ammonia production as well as the strategies for enhanced nitrogen carriers performance are proposed.The preparation methods of nitrides are overviewed,and the nitrogen carrier performance control is evaluated objectively,in order to provide guidance for nitrogen carrier mediated chemical chain synthesis of ammonia and promote the transformation of basic research into industrial technology.

关 键 词：氨 可再生能源 氢能 载氮体 化学链 

分 类 号：TK114[动力工程及工程热物理—热能工程] TK91