A review of ultra-high temperature heat-resistant energetic materials  

作　　者：Rongzheng Zhang Yuangang Xu Feng Yang Pengcheng Wang Qiuhan Lin Hui Huang Ming Lu 

机构地区：[1]School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China [2]Institute of Chemical Materials,China Academy of Engineering Physics,Mianyang 621900,China

出　　处：《Defence Technology（防务技术）》2024年第8期33-57,共25页Defence Technology

基　　金：supported by the National Natural Science Foundation of China(Grant Nos.21975127,22105102,and 22135003);Young Elite Scientist Sponsorship Program by CAST(Grant No.YESS20210074);the Fundamental Research Funds for the Central Universities(Grant No.30921011204)。

摘　　要：Heat-resistant energetic materials refer to a type of energetic materials that possess a high melting point,high stability and operational safety. By studying the structures of these energetic materials has showed that the thermal stability can be enhanced by introducing amino groups to form intra/inter-molecular hydrogen bonds, constructing conjugate systems and designing symmetrical structures. This article aims to review the physical and chemical properties of ultra-high temperature heat-resistant energetic compounds and provide valuable theoretical insights for the preparation of ultra-high temperature heatresistant energetic materials. We also analyze the selected 20 heat-resistant energetic materials with decomposition temperatures higher than 350℃, serving as templates for the synthesis of various highperformance heat-resistant energetic materials.

关 键 词：Heat-resistant energetic materials Organic synthesis CONJUGATED Hydrogen bond Symmetrical structure STABILIZATION 

分 类 号：TQ560[化学工程—炸药化工]