木质素基高效染料吸附材料制备及其性能研究  

Preparation of Lignin-based High Efficiency Dye Adsorption Materials and Their Performance

作　　者：温默涵 徐新 李丽君 黄剑波 张学铭[1] WEN Mohan;XU Xin;LI Lijun;HUANG Jianbo;ZHANG Xueming(Beijing Key Lab of Lignocellulosic Chemistry,Beijing Forestry University,Beijing,100083;China National Pulp and Paper Research Institute Co.,Ltd.,Beijing,100102)

机构地区：[1]北京林业大学林木生物质化学北京市重点实验室,北京100083 [2]中国制浆造纸研究院有限公司,北京100102

出　　处：《中国造纸》2024年第7期74-83,共10页China Pulp & Paper

基　　金：国家自然科学基金项目(22278035)。

摘　　要：本研究采用ZnCl2、KOH和尿素共同活化处理工业碱木质素,经高温碳化(700℃)制备得到木质素基高吸附性能材料(Zn-LB)。将Zn-LB用于亚甲基蓝和甲基橙染料溶液吸附实验,探究了染料种类、吸附温度、多元混合染料体系对Zn-LB吸附性能的影响。结果表明,Zn-LB的比表面积高达2190.3 m^(2)/g。通过Langmuir吸附等温线模型拟合了Zn-LB对亚甲基蓝和甲基橙的最大平衡吸附量分别为1345.9和1732.4 mg/g。此外,Zn-LB对亚甲基蓝的吸附量随温度的升高而升高,表明吸附亚甲基蓝是一个吸热过程;而Zn-LB对甲基橙的吸附则相反,是一个放热过程。The industrial alkali lignin was subjected to co-activation treatment with ZnCl2,KOH,urea,and lignin-based adsorption material with high adsorption capacity(Zn-LB)was prepared by high temperature carbonization(700℃).The prepared material was used in adsorp‐tion experiments with methylene blue and methyl orange dyes to explore the effects of dye type,adsorption temperature,and a multi-compo‐nent dye system on the adsorption capacity of Zn-LB.The results showed that the specific surface area of the prepared Zn-LB samples reached 2190.3 m^(2)/g.The maximum equilibrium adsorption capacities of Zn-LB for methylene blue and methyl orange,as fitted through the Langmuir adsorption isotherm model,were 1345.9 and 1732.4 mg/g,respectively.Additionally,the adsorption capacity for methylene blue increased with increasing temperature,indicating that the adsorption of methylene blue was an endothermic process.Conversely,the adsorption capacity for methyl orange decreased with rising temperature,suggesting an exothermic process.

关 键 词：碱木质素 吸附剂 亚甲基蓝 甲基橙 吸附等温线模型 

分 类 号：TS79[轻工技术与工程—制浆造纸工程]