竹炭掺杂铋系光催化剂的制备及其对有机污染物的降解研究  

Research on Preparation of Bamboo Charcoal Doped Bismuth⁃based Photocatalysts and Their Degradation of Organic Pollutants

作　　者：朱亚玮 房桂干[1,2,3] 盘爱享 尹航[1] 谢章红[5] 沈葵忠 田庆文[1,3,4] ZHU Yawei;FANG Guigan;PAN Aixiang;YIN Hang;XIE Zhanghong;SHEN Kuizhong;TIAN Qingwen(Institute of Chemical Industry of Forestry Products,CAF,Nanjing,Jiangsu Province,210042;Nanjing Forestry University,Nanjing,Jiangsu Province,210037;Shandong Huatai Paper Co.,Ltd.,&Shandong Yellow Triangle Biotechnology Industry Research Institute Co.,Ltd.,Dongying,Shandong Province,257335;College of Light Industry and Food Engineering,Guangxi Key Lab of Clean Pulp&Papermaking and Pollution Control,Guangxi University,Nanning,Guangxi Zhuang Autonomous Region,530004;Sichuan Province Engineering Technology Research Center of Bamboo Pulping and Papermaking,Yibin Paper Industry Co.,Ltd.,Yibin,Sichuan Province,644007)

机构地区：[1]中国林业科学研究院林产化学工业研究所,江苏南京210042 [2]南京林业大学,江苏南京210037 [3]山东华泰纸业股份有限公司&山东黄三角产业技术研究院有限公司,山东东营257335 [4]广西大学轻工与食品工程学院,广西清洁化制浆造纸与污染控制重点实验室,广西南宁530004 [5]宜宾纸业股份有限公司,四川省竹浆造纸工程技术研究中心,四川宜宾644007

出　　处：《中国造纸》2024年第7期191-198,共8页China Pulp & Paper

基　　金：国家重点研发计划(2022YFC2105505);宜宾市竹产业“揭榜挂帅”项目“竹基浆精深加工技术研究与开发”(2022JB009);郴州国家可持续发展议程创新示范区省级专项“揭榜挂帅”项目课题(2022sfq56)。

摘　　要：本研究以竹浆备料废弃物为原料,通过磷酸活化法制得竹炭,再利用水热法制备了竹炭/BiOCl复合催化剂,并探究了竹炭添加量和水热温度对复合催化剂光催化性能的影响。结果表明,竹炭保留了竹子本身的孔道结构,改变竹炭的添加量可实现对竹炭/BiOCl复合催化剂形貌的调控,为吸附污染物提供了良好的条件。竹炭和BiOCl之间发生的强相互作用,显著改善了BiOCl的吸附-光催化性能和氧空位含量,提高了光生电子传输效率,从而优化了复合催化剂的光催化降解效果。在水热温度140℃和竹炭添加量5%的条件下所制复合催化剂5BC-140,其可见光催化性能最佳,对罗丹明B的去除率在30 min内即可达86.5%,一阶动力学常数k为BiOCl的4.2倍,且具有优异的稳定性和可循环性能。In this study,bamboo charcoal was prepared from waste generated during bamboo pulp preparation by phosphoric acid activation method,and then bamboo charcoal/BiOCl composite catalysts were subsequently synthesized via hydrothermal method,and the effects of dos‐age of bamboo charcoal and hydrothermal temperature on the photocatalytic properties of the composite catalysts were systematically investigat‐ed.The results showed that the bamboo charcoal retained the inherent pore structure of bamboo,and changing the dosage of bamboo charcoal could achieve the modulation of the morphology of the bamboo charcoal/BiOCl com‐posite catalyst,which provided a good condition for pollutant adsorption.The pronounced interactions occurring between bamboo charcoal and BiOCl signif‐icantly improved the adsorption-photocatalytic performance and oxygen vacan‐cy content of BiOCl,so that the efficiency of photogenerated electron transfer was enhanced and the photocatalytic degradation of the composite catalyst was optimised.The composite catalyst 5BC-140 observed at the hydrothermal temperature of 140℃and bamboo charcoal dosage of 5%showed the optimal visible photocatalytic properties,with the removal rate of rhodamine B reaching 86.5%within 30 min,the one-mediated kinetic con‐stant k being 4.2 times that of BiOCl,and excellent stability and recyclability.

关 键 词：竹材废弃物 竹炭 光催化 BiOCl 高值化利用 

分 类 号：TS721.2[轻工技术与工程—制浆造纸工程]