电感耦合等离子体质谱法测定锌电解液中铊含量的研究  

Determination of Thallium in Zinc Electrolyte by Inductively Coupled Plasma Mass Spectrometry

作　　者：于亮 杨月 郑丽霞 YU Liang;YANG Yue;ZHENG Li-xia(Zhuzhou Smelting Group Co.,Ltd.,Zhuzhou,412000,China)

机构地区：[1]株洲冶炼集团股份有限公司,湖南株洲412000

出　　处：《世界有色金属》2024年第12期12-14,共3页World Nonferrous Metals

摘　　要：建立了使用电感耦合等离子体质谱仪测定锌湿法冶炼电解液中铊含量的方法,样品经过稀释在稀硝酸介质中,^(205)Tl为测量同位素,以He作为碰撞气体,^(185)Re作内标校正干扰,用工作曲线法计算铊的含量。该方法测定锌电解液中铊含量的检出限为0.2ng/L,相对标准偏差小于5%,方法试验回收率在96%~101.1%之间,具有良好的准确度和精密度。A method for the determinationof Thallium content in zinc hydrometallurgy electrolyte by inductively coupled plasma mass spectrometry was established through experiments.The sample was diluted in dilute nitric acid medium,^(205)Tl was used as the measuring isotope,He was used as collision gas and ^(185)Re was used as internal standard to correct interference,and the thallium content was calculated by standard curve method.The detection limit of thallium content in zinc electrolyte is 0.2ng/L,the relative standard deviation is less than 5%,and the recovery rate of the method test is between 96% and 101.1%,which has good accuracy and precision.

关 键 词：ICP-MS 锌电解液 铊 

分 类 号：O657.63[理学—分析化学]