Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill:Structure modification,binder properties and environmental assessment  

作　　者：Dengfeng Zhao Shiyu Zhang Yingliang Zhao 

机构地区：[1]Department of Mining Engineering,Lyuliang University,Lvliang 033000,China [2]School of Civil and Environmental Engineering,University of Science and Technology Beijing,Beijing 100083,China [3]School of Mining Engineering,Taiyuan University of Technology,Taiyuan 030024,China [4]Department of Civil and Environmental Engineering,The Hong Kong Polytechnic University,Hong Kong 00852,China

出　　处：《International Journal of Minerals,Metallurgy and Materials》2024年第10期2136-2147,共12页矿物冶金与材料学报（英文版）

基　　金：supported from the National Natural Science Foundation of China(No.52304148);the Youth Project of Shanxi Basic Research Program,China(No.202203021212262).

摘　　要：The substantial arsenic(As)content present in arsenic-containing bio-leaching residue(ABR)presents noteworthy environ-mental challenges attributable to its inherent instability and susceptibility to leaching.Given its elevated calcium sulfate content,ABR exhibits considerable promise for industrial applications.This study delved into the feasibility of utilizing ABR as a source of sulfates for producing super sulfated cement(SSC),offering an innovative binder for cemented paste backfill(CPB).Thermal treatment at varying temperatures of 150,350,600,and 800℃ was employed to modify ABR’s performance.The investigation encompassed the examination of phase transformations and alterations in the chemical composition of As within ABR.Subsequently,the hydration characteristics of SSC utilizing ABR,with or without thermal treatment,were studied,encompassing reaction kinetics,setting time,strength development,and microstructure.The findings revealed that thermal treatment changed the calcium sulfate structure in ABR,consequently impacting the resultant sample performance.Notably,calcination at 600℃ demonstrated optimal modification effects on both early and long-term strength attributes.This enhanced performance can be attributed to the augmented formation of reaction products and a densified micro-structure.Furthermore,the thermal treatment elicited modifications in the chemical As fractions within ABR,with limited impact on the As immobilization capacity of the prepared binders.

关 键 词：cemented paste backfill bio-leaching residue arsenic immobilization binder hydration CALCINATION 

分 类 号：X75[环境科学与工程—环境工程] TQ430.7[化学工程] TQ172.1