生物质基平台化合物催化转化制备戊二醇  

Catalytic Transformation of Biomass-Based Platform Compounds to Pentanediols

作　　者：邓佳慧 刘毅[1] 张良清 邱佳容 陈剑锋[1] 曾宪海 Jiahui Deng;Yi Liu;Liangqing Zhang;Jiarong Qiu;Jianfeng Chen;Xianhai Zeng(School of Advanced Manufacturing,Fuzhou University,Jinjiang 362251,China;College of Energy,Xiamen University,Xiamen 361102,China)

机构地区：[1]福州大学先进制造学院,晋江362251 [2]厦门大学能源学院,厦门361102

出　　处：《化学进展》2024年第7期1061-1087,共27页Progress in Chemistry

基　　金：国家自然科学基金项目(No.22108038,21978248);齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室开放基金项目(GZKF202308);泉州市科技计划项目(No.2022N030);福建省自然科学基金项目(No.2022J01573);国家重点研发计划项目(No.2021YFC2101604);广东省重点领域研发计划项目(No.2020B0101070001)资助。

摘　　要：戊二醇(1,2-戊二醇、1,4-戊二醇及1,5-戊二醇等)是全球广泛使用的重要医药化工原料,不仅可以用作杀菌剂丙环唑的中间体和化妆品配方,还是生产表面活性剂、聚酯纤维和医药等产品的关键成分。近年来,随着国内外市场的发展,开发生产戊二醇的需求不断增加,工业上通常采用不可再生的化石原料制备戊二醇,对环境污染严重,因此以可再生的生物质基为原料催化转化制备戊二醇是一种绿色生产工艺,更具有良好的应用前景和研究价值。本文系统总结了近年来以国内外生物质基平台化合物(木糖、糠醛、糠醇、四氢糠醇、γ-戊内酯和乙酰丙酸)为原料催化加氢制备戊二醇的研究现状,对制备戊二醇的催化剂进行了分析总结,从不同催化体系(贵金属和非贵金属)、反应机理、反应路径、反应条件及催化剂的稳定性等方面进行详细阐述,并且在此基础上从绿色环保和经济等多角度出发对完善生物质基制备戊二醇的生产工艺进行了展望,为进一步开发新型、高效、绿色和稳定的催化剂体系提供参考。Pentanediols(1,2-pentanediol,1,4-pentanediol,and 1,5-pentanediol,etc.)are significant pharmaceutical chemicals that are used extensively worldwide.In addition to serving as an intermediate for the fungicide propiconazole and in the production of cosmetic products,they are also employed as key components in the manufacture of surfactants,polyester fibers,and pharmaceutical products.With the development of domestic and foreign markets in recent years,there has been growing demand for pentanediols production.Conventionally,the industrial production of pentanediols relies on non-renewable fossil resources,posing significant environmental concerns.Hence,the catalytic conversion of renewable biomass-based feedstocks to produce pentanediols represents a green production process,promising a brighter application prospect and research significance.This article provides a comprehensive review of recent studies on the catalytic transformation of biomass-based feedstocks(such as xylose,furfural,furfuryl alcohol,tetrahydrofurfuryl alcohol,gamma-valerolactone,and levulinic acid)for pentanediols production.A detailed summary of the catalysts employed for pentanediols synthesis is presented,encompassing various catalytic systems(noble and non-noble metals),reaction mechanisms,pathways,reaction conditions,and catalyst stability.On this basis,perspectives are offered on refining the biomass-derived pentanediols production process,considering sustainability and economics,etc.This review aims to furnish theoretical guidance and beneficial references for further developing novel,efficient,green,and stable catalytic systems.

关 键 词：糠醛 糠醇 四氢糠醇 乙酰丙酸 催化剂 戊二醇 

分 类 号：O643.31[理学—物理化学] O643.32[理学—化学] O643.36