动态光散射测量仪粒度标准物质的研制  

Development of particle size standard materials for dynamic light scattering measuring instruments

作　　者：陈胜利[1] 朱秀芹 CHEN Shengli;ZHU Xiuqin(College of Chemical Engineering and Environment,China University of Petroleum(Beijing),Beijing 102249,China;Beijing Nanowize Standard Materials Co.,Ltd.,Beijing 102200,China)

机构地区：[1]中国石油大学(北京)化学工程与环境学院,北京102249 [2]北京纳微标物科技有限公司,北京102200

出　　处：《中国粉体技术》2024年第5期121-131,共11页China Powder Science and Technology

基　　金：国家自然科学基金项目,编号:2021YFA1501200。

摘　　要：【目的】解决国内尚缺动态光散射测量法专用粒度标准物质的问题。【方法】采用微乳液聚合法合成标称粒径为40、80 nm的态光散射粒度标准物质,标准物质编号分别是QBW12001和GBW12011b;采用动态光散射多家定值法测定2种粒度标准物质的散射光强调和平均粒径,定值结果溯源至动态光散射法(ISO 22412:2017)。【结果】合成的2种粒度标准物质均匀且稳定,散射光强调和平均粒径分别为(40.0±0.5)、(80±2)nm。【结论】不同厂家生产的激光粒度仪测的散射光强度调和平均粒径一致性最好;散射光强度平均粒径一致性较好;体积平均粒径一致性较差;颗粒数目平均粒径一致性最差。Objective As there is currently no dedicated particle size standard material for dynamic light scattering(DLS)measurement in China,manufacturers and users of particle size analyzers in China primarily rely on standard materials produced by Thermo Fisher Scientific.The study aims to develop particle size standard materials for dynamic light scattering particle size analyzers.Methods In this study,dynamic light scattering particle size standard materials with nominal particle sizes of 40 nm and 80 nm were synthesized using microemulsion polymerization.A total of 12 institutes used 14 dynamic light scattering particle size analyzers from different manufacturers to determine the particle size values of the developed standard materials.Results and Discussion The study results showed that the two synthesized polystyrene microspheres exhibited good sphericity and uniform particle size,with stable and homogeneous sample quality.The harmonic mean particle sizes based on scattering light intensity were 40.0±0.5 nm and 80±2 nm,respectively.The measurement uncertainties of the assigned values were comparable to those of similar particle size standard materials from the European Community Bureau of Reference and Thermo Fisher Scientific.Among the dynamic light scattering particle size analyzers produced by different manufacturers,the harmonic mean particle sizes based on scattering light intensity showed the best consistency,the mean particle sizes based on scattering light intensity were relatively consistent,the volume-based mean particle sizes showed less consistency,and the number-based mean particle sizes had the poorest consistency.The repeatability of different mean particle sizes measured by the same instrument followed the same order.Conclusion Two types of dynamic light scattering polystyrene microsphere particle size standard materials,with sizes of 40 nm and 80 nm,were developed.These standard materials exhibit good sphericity,uniform particle size,and stable sample quality.The harmonic mean particle sizes based

关 键 词：粒度 标准物质 聚苯乙烯乳胶 动态光散射 

分 类 号：TB4[一般工业技术] TQ577.77[化学工程—精细化工]