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作 者:王立 岳清政 郭继香[1] 陈祥伟 李驰 高晨豪 WANG Li;YUE Qingzheng;GUO Jixiang;CHEN Xiangwei;LI Chi;GAO Chenhao(Unconventional Petroleum Research Institute,China University of Petroleum,Beijing 102249,China;Donghe Oil and Gas Management Area,PetroChina Tarim Oilfield Branch,Kuerele 841000,Xinjiang,China)
机构地区:[1]中国石油大学(北京)非常规油气科学技术研究院,北京102249 [2]中石油塔里木油田分公司东河采油气管理区,新疆库尔勒841000
出 处:《精细化工》2024年第9期1909-1918,共10页Fine Chemicals
基 金:国家自然科学基金项目(52174047);中石化基金资助项目(P23138)。
摘 要:随着纳米技术的持续发展,磁性聚合物微球作为一种磁响应型纳米材料,在石油工业中展现出极具潜力的应用前景。该文对磁性聚合物微球的多样化结构类型进行了系统的概述,对单体聚合法、活性聚合法进行了详细介绍,并分析了相应的技术特征及其优势与局限性。评述了磁性聚合物微球在油水分离、高效脱硫、催化改质和智能驱油石油应用领域的最新研究成果和技术进展,总结了当前磁性聚合物微球在石油工业应用中所面临的挑战,并对未来的发展趋势进行了展望。未来的研究应侧重于创新制备技术,对磁性核心的表面进行改性、对聚合物外层基团进行精准设计,以提升材料的磁性质量和在石油环境中的稳定性。此外,对磁性聚合物微球的性能进行精细调控,以实现高效率和目标导向的应用效果,即研发具备高磁含量、单一粒径分布、表面易于功能化且具备可调节亲/疏水性质的磁性聚合物微球,以满足石油工业不同场景下的需求。With the continuous advancement of nanotechnology,magnetic polymer microspheres,as magnetically responsive nanomaterials,have shown promising application prospects in the petroleum industry.Here,the diverse structural types of magnetic polymer microspheres were systematically overviewed.The monomer polymerization and living polymerization were detailly introduced,as well as the corresponding technical characteristics,advantages,and limitations were analyzed.Furthermore,the latest research findings and technological developments of magnetic polymer microspheres in petroleum applications,including oil-water separation,high-efficiency desulfurization,catalytic modification,and intelligent oil recovery were reviewed,while the current challenges faced by magnetic polymer microspheres in petroleum industry were summarized,along with a prospective outlook on future research directions.It was suggested that future research should focus on innovative fabrication techniques,surface modification of the magnetic core and precise design of the polymer's outer layer groups to improve the material's magnetic quality and stability in petroleum environments.In addition,magnetic polymer microspheres should be fine-tuned to achieve high efficiency and target-oriented application effects,in other words,magnetic polymer microspheres with high magnetic content,uniform particle size distribution,surface functionality,and adjustable hydrophilic/hydrophobic properties should be developed to meet the diverse requirements of the petroleum industry.
关 键 词:纳米磁性聚合物微球 石油开采 发展方向 研究进展
分 类 号:TE39[石油与天然气工程—油气田开发工程] TQ423[化学工程]
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