Recent Advances in the Electrochemical Defluorinative Transformations of C-F Bonds  

作　　者：Qinhui Wan Rui-Xue Liu Zhongyi Zhang Xia-Die Wu Zhong-Wei Hou Lei Wang 

机构地区：[1]Advanced Research Institute and Schoolof Pharmaceutical Sciences,Taizhou University,Jiaojiang,Zhejiang 318000,China [2]Department of Chemistry,Southern University of Science and Technology,henzhen,Guangdong 518055,China [3]College of Material Chemistry and Chemical Engineering,Key Laboratory of Organosilicon Chemistry and Material Technology Ministryof Education,Hangzhou Normal University,Hangzhou,Zhejiang 311121,China

出　　处：《Chinese Journal of Chemistry》2024年第16期1913-1928,共16页中国化学（英文版）

基　　金：the Natural Science Foundation of Zhejiang Province(LQ22B020005,LZ22B020003);the National Natural Science Foundation of China(22101201,22071171)for financial support of this work.

摘　　要：Organic fluorine compounds are ubiquitous and pivotally important organic molecules,yet their activation and transformation have long been a formidable challenge due to the high energy and low reactivity of C-F bonds.Organic electrosynthesis,an environmentally benign synthetic method in organic chemistry,enables a myriad of chemical transformations without the need for external redox reagents.In recent years,organic electrochemistry has emerged as a powerful tool for achieving the activation and transformation of C-F bonds in fluorine-containing compounds.This review aims to succinctly recapitulate the latest advancements in the electrochemical defluorinative transformations of C-F bonds and to delve into the reaction design,mechanistic insights,and developmental prospects ofthese methods.

关 键 词：Organic electrochemistry ELECTROREDUCTION DEFLUORINATION C-F bond activation Organic fluorine compounds 

分 类 号：O646[理学—物理化学]