84%王铜水分散粒剂中镉、铅、砷分析方法研究  

Study on the Analysis Method of Cadmium,Lead and Arsenic in 84%Copper Oxychloride Water Dispersible Granules

作　　者：刘凤娇 赵广义 赵波 Liu Fengjiao;Zhao Guangyi;Zhao Bo(Shandong VeriSign Test Detection Co.,Ltd,Jinan Shandong 250119,China;Association of Pesticide Industry,Shandong Province,Jinan Shandong 250013,China)

机构地区：[1]山东威瑞信试验检测有限公司,山东济南250119 [2]山东省农药行业协会,山东济南250013

出　　处：《农药科学与管理》2024年第9期26-29,41,共5页Pesticide Science and Administration

摘　　要：本文采用原子吸收分光光度法和原子荧光光谱法,测定84%王铜水分散粒剂中镉、铅、砷的含量。以空气—乙炔火焰原子吸收分光光度法,于228.8 nm波长处,测定镉含量,于283.3 nm波长处测定铅含量;以氩气—砷空心阴极灯原子荧光光谱法测定砷含量。结果表明,该分析方法的线性相关系数分别为0.99482、0.99986、0.99737,标准偏差为0.039、0.18、0.0052,变异系数为5.3%、5.6%、3.2%,平均回收率分别为98.2%、94.5%、101.9%。该方法简便快捷,灵敏度、精密度和准确度高,适用于镉、铅、砷的定量分析。The content of cadmium,lead and arsenic in 84%copper oxychloride water dispersible granules(WG)was determined by atomic absorption spectrophotometry and atomic fluorescence spectrometry.Cadmium content was determined at 228.8nm and the lead content at 283.3nm by airacetylene flame atomic absorption spectrometry.The content of arsenic was determined by argon As hollow cathode lamp atomic fluorescence spectrometry.The results showed linear correlation coefficients of 0.99482,0.99986 and 0.99737,standard deviations of 0.039,0.18 and 0.0052,coefficient of variation of 5.3%,5.6%and 3.2%,and average recoveries of 98.2%,94.5%and 101.9%for cadmium,lead,and arsenic,respectively.The method is simple,rapid,sensitive,precise and accurate,making it suitable for the quantitative analysis of cadmium,lead and arsenic.

关 键 词：镉 铅 砷 火焰原子吸收 原子荧光 分析 

分 类 号：S482.2[农业科学—农药学]