碱促进CO_(2)参与C-H键羰基化反应研究进展  

Progress in Study of Carbonylation Reactions of C-H Bonds Involving CO_(2) Promoted by Alkali

作　　者：谢锈玫 陈雪玲 李俊杰 覃镜 巩少轩 敬方舟 张振 XIE Xiumei;CHEN Xueling;LI Junjie;QIN Jing;GONG Shaoxuan;JING Fangzhou;ZHANG Zhen(School of Mechanical Engineering,Chengdu University,Chengdu 610106,China;Engineering Research Center of Resource Exploitation and Utilization of Sichuan-Xizang Characteristic Medicinal Plant,Chengdu University,Chengdu 610106,China)

机构地区：[1]成都大学机械工程学院,四川成都610106 [2]成都大学川藏特色药用植物资源开发利用工程研究中心,四川成都610106

出　　处：《成都大学学报（自然科学版）》2024年第3期231-237,共7页Journal of Chengdu University（Natural Science Edition）

基　　金：四川省自然科学基金面上项目(2022NSFSC0200);四川省科技创新苗子工程项目(MZGC20230100)。

摘　　要：碱促进CO_(2)参与C-H键羰基化反应因反应体系简洁,最终产物重要而得到了较大的发展,但同时该类反应存在反应温度高与碱用量大等诸多问题,因而系统地对此类反应进行总结和归纳对于问题的解决至关重要.基于此,将CO_(2)参与的羰基化反应分为内酯化反应和内酰胺化反应2大类(其对应的产物分别为酯类和内酰胺类杂环化合物),并依次对各类反应的最新研究进展进行综述,以期为该领域的研究和发展提供借鉴,并在最后对该领域的发展提出了展望.The carbonylation reaction of C-H bond involving CO_(2) promoted by alkali has gained great development due to the simplicity of the reaction system and the importance of the final product.However,there are still many problems to be solved,such as high reaction temperature and the use of a large amount of alkali.Therefore,a systematic summary and the generalization of this type of reaction is essential for the solution to these problems.Based on this,this paper categorizes the carbonylation reactions involving CO_(2) into two major types:lactonization reaction and lactamization reaction(resulting in ester and cyclic amide compounds,respectively),and provides a comprehensive review of the latest research progress for each type of reaction.It is hoped that this will provide necessary help and reference for the research and development in this field.Finally,at the end of the article,the development in this field is analyzed and prospected.

关 键 词：二氧化碳 羰基化 内酯化反应 内酰胺化反应 

分 类 号：TQ253.2[化学工程—有机化工] TQ460.1