固体氧化物燃料电池Ruddlesden-Popper型氧化物阳极的研究进展  

Recent advances in Ruddlesden-Popper oxide for solid oxide fuel cells anodes

作　　者：渠吉发 王旭 张静 时焕岗 谭文轶 QU Jifa;WANG Xu;ZHANG Jing;SHI Huangang;TAN Wenyi(School of Environmental Engineering,Nanjing Institute of Technology,Nanjing 211167,China;School of Energy and Power Engineering,Nanjing Institute of Technology,Nanjing 211167,China;Xuzhou University of Technology,Xuzhou 221018,China)

机构地区：[1]南京工程学院环境工程学院,南京211167 [2]南京工程学院能源与动力工程学院,南京211167 [3]徐州工程学院,江苏徐州221018

出　　处：《功能材料》2024年第9期9078-9086,9110,共10页Journal of Functional Materials

基　　金：江苏省高等学校基础科学(自然科学)研究面上项目(21KJB530012);江苏省高等学校基础科学(自然科学)研究重大项目(23KJA610003);江苏省配电网智能技术与装备协同创新中心开放基金项目(XTCX202210)。

摘　　要：Ruddlesden-Popper(RP)型钙钛矿氧化物具有独特的理化性质,被认为是一种极具潜力的固体氧化物燃料电池(SOFCs)阳极材料,但是多数现有RP型钙钛矿存在不耐还原、催化氧化活性或稳定性不足等问题。在简要介绍RP型氧化物的基础上,总结出其结构可调和性质特异的内在机理,基于材料微观结构的维度、离子取代位点、制备工艺特性等系统地介绍了近年其作为SOFCs阳极的研究进展,并对制备RP型材料使用的相转变法及提升催化活性的原位析出进行了梳理与探讨,重点分析了RP型钙钛矿氧化物用于SOFCs阳极的设计理念和目前仍然存在的问题。最后指出利用异价离子取代、理论实践结合、充分利用氧非计量比是开发耐还原且具有高催化活性和稳定性的新型RP阳极的重要策略。Ruddlesden-Popper(RP)perovskite oxide has a set of distinct physicochemical characteristics that make it a highly promising anode for solid oxide fuel cells(SOFCs).However,it is hard to use most RP perovskites directly in anodes because they lack reduction resistance,catalytic activity or stability.This review summarizes the internal mechanism of structure adjustability and properties richness of RP oxide based on the brief introduction of its characteristics,and then systematically introduces recent advances in RP oxide as an anode for SOFCs based on the dimension of microstructure,ion substitution sites and preparation process characteristics.Then reviews and discusses the ingenious phase transformation method used in preparing materials and in situ precipitation to improve catalytic activity,and extensively analyzes the design concept of the RP materials and the existing problems.Finally,this review indicates that the substitution with heterovalent ion,the combination of theory and practice,the full use of oxygen non-stoichiometric ratio and hydroxylation ability of RP oxide are important strategies to develop new RP anodes with higher reduction resistance,catalytic activity and stability.

关 键 词：固体氧化物燃料电池 Ruddlesden-Popper型钙钛矿氧化物 阳极 电化学 催化 稳定性 

分 类 号：TQ152[化学工程—电化学工业]