FDCA,FDME,2,5-呋喃二甲酸聚酯的工业开发及应用研究进展  

Industrial development and research of FDCA,FDME and FDCA based polyester

作　　者：陈锡荣[1] Chen Xirong(SINOPEC Chemical Department,Beijing 100728,China)

机构地区：[1]中国石油化工股份有限公司化工事业部,北京100728

出　　处：《合成树脂及塑料》2024年第5期68-72,共5页China Synthetic Resin and Plastics

摘　　要：具有芳杂环结构的2,5-呋喃二甲酸(FDCA)与精对苯二甲酸(PTA)结构类似,可广泛用于聚酯、聚酰胺、金属有机骨架材料、医药化学品合成、增塑剂等方面,在多个领域成为PTA理想的生物基替代品。目前,市场尚无FDCA,2,5-呋喃二甲酸二甲酯(FDME),聚2,5-呋喃二甲酸乙二酯(PEF)的工业化产品,FDCA,PEF由于生产成本高、技术难度大,仍处于研究阶段。欧洲、北美等国家在持续推动FDCA,FDME及PEF商业化工作中保持领先,其中,PEF对CO_(2),O_(2),H_(2)O的阻隔性能极好,将在生鲜食品包装领域有着广阔的应用前景。2,5-Furan dicarboxylic acid(FDCA)with aromatic heterocyclic structure is similar to purified terephthalic acid(PTA)structure,which can be widely used in polyester,polyamide,metal-organic framework materials,pharmaceutical synthesis,and plasticizers,which has become an ideal bio-based alternative to PTA in many fields.There are no FDCA,dimethyl furan-2,5-dicarboxylate(FDME)and poly(ethylene 2,5-furandicarboxylate)(PEF)industrialized products in the market,FDCA and PEF are still in the developing stage due to high production costs and technical difficulties.European and American countries continue to lead in the commercialization of FDCA,FDME and PEF,among which PEF has excellent barrier performance to CO_(2),O_(2) and H_(2)O,it will have broad application prospects in the fresh packaging industry.

关 键 词：2 5-呋喃二甲酸 2 5-呋喃二甲酸二甲酯 聚2 5-呋喃二甲酸乙二酯 聚酯 发展趋势 

分 类 号：TQ323.4[化学工程—合成树脂塑料工业]