A Composite Elastomer with Photo-responsive Shape Memory and Programmable Hygroscopic Actuation Functionalities  

作　　者：Xiang-Xi Cui Li Shang Zhong-Wen Liu Zhao-Tie Liu Jin-Qiang Jiang Guo Li 

机构地区：[1]Key Laboratory of Syngas Conversion of Shaanxi Province,School of Chemistry and Chemical Engineering,Shaanxi Normal University,Xi’an,710062,China

出　　处：《Chinese Journal of Polymer Science》2024年第10期1470-1478,I0009,共10页高分子科学（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(Nos.51803115 and 21636006);the Fundamental Research Funds for the Central Universities(Nos.GK201901001,2021CSLY008,2021CSZL003 and GK202103032);the Innovation Capability Support Program of Shaanxi(No.2020TD-024)。

摘　　要：Developing hydroscopic actuators with simultaneous high elasticity,shape programmability and tunable actuating behaviors are highly desired but still challenging.In this study,we propose an orthogonal composite design to develop such a material.The developed composite elastomer comprises carboxyl group-grafted polystyrene-block-poly(ethylene-co-butylene)-block-polystyrene(SEBS-g-COOH)as the elastic substrate,and a synthesized azobenzene derivative as the functional filler(Azo12).By surface treatment using acidic and base solutions,the carboxyl groups on the surface can reversibly transform into carboxylate groups,which render the composite tunable hygroscopic actuating functionality.On another aspect,the added filler undergoes trans-to-cis isomerization when exposed to UV light irradiation,leading to liquefaction of the crystalline aggregates formed by Azo12 molecules.The liquefied Azo12 molecules can autonomously resotre their trans form and reform the crystalline structure.This reversible change in crystralline structure is utilized to realize the shape memory property,and 5 wt%of Azo12addition is adequate for the composite to exhibit photo-responsive shape memory behavior without compromising much of the elasricity.The regualtion of external geometry by shape memory effect is effective in altering the actuating behavior.The proposed method can be extend to designing different composites with the demonstrated functionalities.

关 键 词：Actuator Shape memory PHOTO-RESPONSIVE Hygroscopic responsive AZOBENZENE 

分 类 号：TQ334[化学工程—橡胶工业]