Surfactant-metal-organic framework complexes and their derivatives:advances in electrocatalysis  

作　　者：Yining Liu Mengying Wang Zuozhong Liang Haoquan Zheng 

机构地区：[1]Key Laboratory of Applied Surface and Colloid Chemistry,Ministry of Education,School of Chemistry and Chemical Engineering,Shaanxi Normal University,Xi’an 710119,China

出　　处：《Science China Chemistry》2024年第10期3209-3222,共14页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(22178213,22375120,21975148,21601118);the Innovation Capability Support Program of Shaanxi(2023KJXX-018);the Fundamental Research Funds for the Central Universities(GK202207007,GK202309002,GK202103042);the Natural Science Basic Research Program of Shaanxi(2022JC-05);the Natural Science Foundation of Shaanxi Province of China(2022JM-069);the Starting Research Funds of Shaanxi Normal University;the 111 Project(B14041);the International Joint Research Center on Advanced Characterizations of Xi'an City。

摘　　要：Metal-organic frameworks(MOFs)and their derivatives received more and more attention due to the diverse morphologies,rich porous structures,and tunable metal active sites,which have been widely used in energy-related electrocatalytic reactions.Surfactants,a class of compounds with hydrophilic and hydrophobic portions in the molecular structure,are able to modulate the properties of liquid and solid surfaces.Surfactants play a crucial role in controlling the shape and size of MOFs,which helps optimize electrocatalytic performance,especially in improving the exposure and accessibility of catalytic active sites.In this review,we first outline the types and applications of surfactants.Second,we describe the interface modulation and reaction mechanism of different surfactants during the forming of MOFs and their derivatives.Finally,we discuss the current applications of surfactant-modified MOFs and their derivatives in electrocatalysis.This review provides a better understanding of surfactantassistant structure regulation and electrocatalytic activity study of MOFs and their derivatives.

关 键 词：metal-organic frameworks SURFACTANTS interface modulation ELECTROCATALYSIS 

分 类 号：O641.4[理学—物理化学] TQ423[理学—化学]