3-氨基吡唑-4-羧酸Ni(Ⅱ)基配合物对高氯酸铵催化作用的研究  

The catalytic effect of a Ni(Ⅱ) complex towards ammonium perchlorate based on 3-aminopyrazole-4-carboxylic acid

作　　者：马娟 杨燕红 梁家维 麻晓霞[1] MA Juan;YANG Yanhong;LIANG Jiawei;MA Xiaoxia(College of Chemistry and Chemical Engineering of Ningxia University,Yinchuan Ningxia 750021,China)

机构地区：[1]宁夏大学化学化工学院,宁夏银川750021

出　　处：《石油化工应用》2024年第9期97-100,共4页Petrochemical Industry Application

基　　金：宁夏大学研究生创新项目(CXXM202416)。

摘　　要：以含能配体3-氨基吡唑-4-羧酸(H2apza)构筑了一种新型Ni(Ⅱ)基配合物Ni(Hapza)2(H2O)4,利用元素分析、红外光谱、紫外光谱、热重分析等对其进行结构表征。利用差示扫描量热测试和Kissinger方法研究了配合物对高氯酸铵(AP)的催化性能,结果表明,该配合物对AP具有良好的催化作用。A novel Ni(Ⅱ)based complex Ni(Hapza)2(H2O)4 was constructed by an energetic ligand 3-aminopyrazole-4-carboxylic acid(H2apza).Elemental analysis,infrared spectroscopy,ultraviolet spectroscopy and thermogravimetric analysis were used to determine the structure of the complex.The catalytic performance of the complex towards ammonium perchlorate(AP)was studied using differential scanning calorimetry and Kissinger method,which indicate that the complex has a good catalytic effect on AP.

关 键 词：配合物 3-氨基吡唑-4-羧酸 高氯酸铵 

分 类 号：O626.28[理学—有机化学]