腰果酚基阻燃高分子材料研究进展  

Research progress in cardanol-based flame retardant polymer materials

作　　者：王鑫[1] 牛浩鑫 胡源[1] WANG Xin;NIU Haoxin;HU Yuan(State Key Laboratory of Fire Science,University of Science and Technology of China,Hefei 230027,China)

机构地区：[1]中国科学技术大学火灾科学国家重点实验室,合肥230027

出　　处：《材料工程》2024年第10期24-33,共10页Journal of Materials Engineering

基　　金：国家自然科学基金面上项目(22075265,22375195);中国科学院青年创新促进会会员项目(2021459)。

摘　　要：随着全球环保意识的提高和国家碳达峰战略的提出,利用可再生生物基资源制备阻燃高分子材料受到广泛关注。腰果酚来源广泛、价格低廉,具有多个高活性反应基团,有望用于商业化制备阻燃高分子材料。本文综述了用于改性聚氯乙烯、不饱和聚酯和环氧树脂的腰果酚基阻燃添加剂的制备方法,同时对比分析了其性能。总结归纳了阻燃腰果酚基环氧树脂、阻燃腰果酚基苯并噁嗪、阻燃腰果酚基紫外光固化涂层、阻燃腰果酚基聚氨酯泡沫和阻燃腰果酚基酚醛泡沫的最新研究进展。指出制备综合性能优异的多功能阻燃腰果酚基高分子材料是未来研究的重点方向。With the increasing awareness of environmental protection and the proposal of the national carbon peak strategy,the use of renewable bio-based resources for the preparation of flame retardant polymer materials has received widespread attention.Cardanol is an abundant and cost-effective biomass with multiple highly reactive functional groups,which is expected to be used for the preparation of commercial flame retardant polymeric materials.The preparations of cardanol-based flame retardant additives for modifying polyvinyl chloride,unsaturated polyester thermosets,and epoxy thermosets were summarized.Their performances were comparatively analyzed.The recent research progress in flame retardant cardanol-based epoxy thermosets,flame retardant cardanol-based benzoxazines,flame retardant cardanol-based ultraviolet-curable coatings,flame retardant cardanol-based polyurethane foams,and flame retardant cardanol-based phenolic foams were summarized.It is pointed out that the preparation of multifunctional flame retardant cardanol-based polymer materials with excellent comprehensive performance is the key direction of future research.

关 键 词：高分子材料 腰果酚 阻燃添加剂 本征阻燃 

分 类 号：TQ322[化学工程—合成树脂塑料工业] TB32[一般工业技术—材料科学与工程]