Sustainable electrosynthesis: Enantioselective electrochemical Rh(Ⅲ)/chiral carboxylic acid-catalyzed oxidative C–H cyclization coupled with hydrogen evolution reaction  

作　　者：Xinghui Yao Zhouyu Wang Da-Gang Yu 

机构地区：[1]Department of Chemistry,Xihua University,Chengdu 610039,China [2]Key Laboratory of Green Chemistry&Technology of Ministry of Education,College of Chemistry,Sichuan University,Chengdu 610064,China

出　　处：《Chinese Chemical Letters》2024年第9期1-3,共3页中国化学快报（英文版）

摘　　要：Chiral compounds play a crucial role in the development of pharmaceuticals,pesticides,fragrances,and materials due to their unique stereochemical configurations.Asymmetric catalysis,which employs chiral catalysts to favor the production of one enantiomer over its mirror image,has emerged as a pivotal technique in the synthesis of chiral compounds[1].However,traditional asymmetric methods sometimes rely on environmentally harmful reducing or oxidizing agents,presenting a considerable challenge in the pursuit of green chemistry.

关 键 词：CHIRAL OXIDATIVE catalyzed 

分 类 号：O621.251[理学—有机化学]