生物基无卤阻燃环氧树脂的研究进展  

Research Progress on Bio-based Halogen-free Flame Retardant Epoxy Resin

作　　者：潘建辉 颜春 祝颖丹 刘东 徐海兵 沈江南 PAN Jian-hui;YAN Chun;ZHU Ying-dan;LIU Dong;XU Hai-bing;SHEN Jiang-nan(College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,China;Zhejiang Provincial Key Laboratory of Robotics and Intelligent Manufacturing Equipment Technology,Ningbo Institute of Material Technology and Engineering,Chinese Academy of Sciences,Ningbo 315201,China)

机构地区：[1]浙江工业大学化学工程学院,杭州310014 [2]浙江省机器人与智能制造装备技术重点实验室,中国科学院宁波材料技术与工程研究所,宁波315201

出　　处：《高分子通报》2024年第10期1371-1387,共17页Polymer Bulletin

基　　金：国家自然科学基金(基金号U23A2067);宁波市重点研发计划项目(项目号2023Z024);宁波市科技创新2025重大专项(项目号2022Z102)。

摘　　要：随着全球能源危机和环境污染日益严重,利用生物质原料设计合成生物基阻燃剂和环氧单体,将其对环氧树脂进行阻燃改性已受到广泛关注。本文综述了基于生物质的添加型、反应型和本征型阻燃环氧树脂的研究进展,详细介绍了生物基阻燃剂与阻燃环氧单体的合成,分析了三种阻燃方式下阻燃环氧树脂的性能及其阻燃机理,进一步对生物基阻燃环氧树脂的发展趋势进行了展望。With the increasing global energy crisis and environmental pollution,the design and synthesis of bio-based flame retardants and epoxy monomers using biomass raw materials for flame retardant modification of epoxy resin have attracted widespread attention.This paper provides an overview of the research progress including additive,reactive and intrinsic flame retardant epoxy resins based on biomass.The synthesis of bio-based flame retardants and flame retardant epoxy monomers are described,and the performance and flame retardant mechanism of bio-based flame retardant epoxy resin using three flame retardant modes are analyzed.Furthermore,the development trend of bio-based flame retardant epoxy resin is prospected.

关 键 词：环氧树脂 生物基无卤阻燃剂 本征阻燃 阻燃性能 阻燃机理 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]