A high-entropy-designed cathode with V^(5+)-V^(2+) multi-redox for high energy density sodium-ion batteries  

作　　者：Xiang Ding Xiaofen Yang Yibing Yang Liangwei Liu Yi Xiao Lili Han 

机构地区：[1]College of Chemistry and Materials Science,Fujian Normal University.Fuzhou 350007,Fujian,China [2]State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,Fujian,China

出　　处：《Journal of Energy Chemistry》2024年第10期429-437,I0008,共10页能源化学（英文版）

基　　金：financially supported by the National Key Research and Development Program of China (2022YFA1505700,2019YFA0210403);the National Natural Science Foundation of China (52102216);the Natural Science Foundation of Fujian Province (2022J01625,2022-S-002);the Innovation Training Program for College Students (202310394020,cxxl-2023097,cxxl-2024131,cxxl-2024136)。

摘　　要：Na_(3)V_(2)(PO_(4))_(3)(NVP)is gifted with fast Na^(+)conductive NASICON structure.But it still suffers from low electronic conductivity and inadequate energy density.Herein,a high-entropy modification strategy is realized by doping V^(3+)site with Ga^(3+)/Cr^(3+)/Al^(3+)/Fe^(3+)/In^(3+)simultaneously(i.e.Na_(3)V_(2-x)(GaCrAlFeIn)_x(PO_(4))_(3);x=0,0.04,0.06,and 0.08)to stimulate the V^(5+)■V^(2+)reversible multi-electron redox.Such configuration high-entropy can effectively suppress the structural collapse,enhance the redox reversibility in high working voltage(4.0 V),and optimize the electronic induced effect.The in-situ X-ray powder diffraction and in-situ electrochemical impedance spectroscopy tests efficaciously confirm the robust structu ral recovery and far lower polarization throughout an entire charge-discharge cycle during 1.6-4.3 V,respectively.Moreover,the density functional theory calculations clarify the stronger metallicity of high-entropy electrode than the bare that is derived from the more mobile free electrons surrounding the vicinity of Fermi level.By grace of high-entropy design and multi-electron transfer reactions,the optimal Na_(3)V_(1.7)(GaCrAlFeIn)_(0.06)(PO_(4))_(3)can exhibit perfect cycling/rate performances(90.97%@5000 cycles@30 C;112 mA h g^(-1)@10 C and 109 mA h g^(-1)@30 C,2.0-4.3 V).Furthermore,it can supply ultra-high185 mA h g^(-1)capacity with fa ntastic energy density(522 W h kg^(-1))in half-cells(1.4-4.3 V),and competitive capacity(121 mA h g^(-1))as well as energy density(402 W h kg^(-1))in full-cells(1.6-4.1 V),demonstrating enormous application potential for sodium-ion batteries.

关 键 词：Na_(3)V_(2)(PO_(4))_(3) High-entropy V^(5+)■V^(2+)multi-redox High energy density Sodium-ion batteries 

分 类 号：TB34[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]