Modification,application and expansion of electrode materials based on cobalt telluride  

作　　者：Huilin Fan Yao Dai Xiaoyun Xue Runguo Zheng Yuan Wang Hamidreza Arandiyan Zhiyuan Wang Zongping Shao Hongyu Sun Yanguo Liu 

机构地区：[1]School of Materials Science and Engineering,Northeastern University,Shenyang 110004,Liaoning,China [2]School of Resources and Materials,Northeastern University at Qinhuangdao,Qinhuangdao 066004,Hebei,China [3]Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province,Northeastern University at Qinhuangdao,Qinhuangdao 066004,Hebei,China [4]Department of Chemical Engineering,The University of Melbourne,Melbourne,VIC 3010,Australia [5]Centre for Advanced Materials and Industrial Chemistry(CAMIC),School of Science,RMIT University,Melbourne,VIC 3000,Australia [6]Laboratory of Advanced Catalysis for Sustainability,School of Chemistry,University of Sydney,Sydney,NSW 2006,Australia [7]WA School of Mines:Minerals,Energy and Chemical Engineering,Curtin University,Perth,WA 6845,Australia

出　　处：《Journal of Energy Chemistry》2024年第10期710-737,I0015,共29页能源化学（英文版）

基　　金：financially supported by the National Natural Science Foundation of China (Nos.52171202,52177208,52071073);the financial support from CSIRO;the Department of Climate Change,Energy,the Environment and Water (DCCEEW)Australian Government;the Australian Hydrogen Research Network (AHRN);the Australian Research Council (DE230100327 and LP220200583);the support from the DCCEEW International Clean Innovation Researcher Networks Grant (ICIRN000011)。

摘　　要：Metal(Li,Na,K,Al)-ion batteries and lithium-sulfur and lithium-tellurium batteries are gaining recognition for their eco-friendly characteristics,substantial energy density,and sustainable attributes.However,the overall performance of rechargeable batteries heavily depends on their electrode materials.Transition metal tellurides have recently gained significant attention due to their high electrical conductivity and density.Cobalt telluride has received the most extensive research due to its catalytic activity,unique magnetic properties,and diverse composition and crystal structure.Nevertheless,its limited conductivity and significant volume variation contribute to electrode structural deterioration and rapid capacity decline.This review comprehensively summarizes recent advances in rational design and synthesis of modified cobalt telluride-based electrodes,encompassing defect engineering(Te vacancies,cation vacancies,heterointerfaces,and homogeneous interfaces)and composite engineering(derived carbon from precursors,carbon fibers,Mxene,graphene nanosheets,etc.).Particularly,the intricate evolution mechanisms of the conversion reaction process during cycling are elucidated.Furthermore,these modified strategies applied to other transitional metal tellurides,such as iron telluride,nickel telluride,zinc telluride,copper telluride,molybdenum telluride,etc.,are also thoroughly summarized.Additionally,their application extends to emerging aqueous zinc-ion batteries.Finally,potential challenges and prospects are discussed to further propel the development of transition metal tellurides electrode materials for next-generation rechargeable batteries.

关 键 词：Rechargeable batteries Transition metal tellurides Cobalt telluride Defect engineering Composite engineering 

分 类 号：TB34[一般工业技术—材料科学与工程] TM912[电气工程—电力电子与电力传动]