MOFs基材料在电催化还原CO_(2)中的应用  

Application of MOFs-based materials in electrocatalytic reduction of CO_(2)

作　　者：梁梅 祝贺 张宸铭 苏永庆[1] 张义成 LIANG Mei;ZHU He;ZHANG Chenming;SU Yongqing;ZHANG Yicheng(Faculty of Chemistry and Chemical Engineering,Yunnan Normal University,Kunming 650500,China)

机构地区：[1]云南师范大学化学化工学院,云南昆明650500

出　　处：《应用化工》2024年第9期2202-2205,2210,共5页Applied Chemical Industry

基　　金：国家自然科学基金项目(21763034,21163025)。

摘　　要：介绍了金属有机框架(MOFs)基材料用于电催化还原CO_(2)(eCO_(2)RR)的研究进展和相关催化剂的制备方法,对比了不同结构MOFs基催化材料在eCO_(2)RR的催化活性、催化稳定性以及产物选择性方面的表现。指出MOFs材料因具有周期性结构的催化活性位点和较高的CO_(2)吸附性能被广泛应用于电催化领域,合理设计高活性、高选择性的CO_(2)还原电催化剂以实现高效的CO_(2)减排,对减少全球温室气体的排放具有重要意义。The research progress of metal organic frameworks(MOFs)materials been used in electrochemical CO_(2) Reduction Reaction(eCO_(2)RR)and the preparation methods of related catalysts were introduced.The catalytic activity,catalytic stability and product selectivity of eCO_(2)RR based MOFs with different structures were compared.It pointed out that MOFs could be widely used in electrocatalytic field because of their periodic catalytic active sites and high CO_(2) adsorption properties.It had an important significance to design CO_(2) reduction electrocatalysts with high activity and selectivity to reduce CO_(2) emission.

关 键 词：MOFS 制备 电催化还原 CO_(2) 

分 类 号：TQ15[化学工程—电化学工业] TQ151