Visible-light-induced Synthesis of Organic Peroxides via Decarboxylative Couplings of Carboxylic Acids,Alkenes and tert-Butyl Hydroperoxide  

作　　者：HUANG Qiuwei LOU Chenhao LV Leiyang LI Zhiping 

机构地区：[1]Key Laboratory of Advanced Light Conversion Materials and Biophotonics,School of Chemistry and Life Resources,Renmin University of China,Beijing,100872,P.R.China

出　　处：《Chemical Research in Chinese Universities》2024年第5期863-873,共11页高等学校化学研究（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.22071266,22201300).

摘　　要：Herein,we present a photoinduced,CeCl_(3)-catalyzed three-component decarboxylative reaction that couples carboxylic acids,alkenes and tert-butyl hydroperoxide for the formation of various organic peroxides.The ligand-to-metal charge transfer(LMCT)excitation mode allows the decarboxylative alkylation-peroxidation reaction to occur under mild conditions,and is well applicable to primary,secondary and tertiary carboxylic acids and styrene derivatives.

关 键 词：Visible-light catalysis Difunctionalization Carboxylic acid ALKENE Organic peroxide 

分 类 号：O62[理学—有机化学]